Results 151 to 160 of about 16,319 (283)
Infrared multiple photon dissociation spectroscopy is used to study the activation of CO2 on Cu‐, Co‐, and Y‐oxide clusters. While CO2 activation is not possible on cationic clusters, the binding motif on anionic clusters depends on a fine interplay between the nature and energetic location of the molecular orbitals and the charge (oxidation state) on ...
Pavol Mikolaj +2 more
wiley +1 more source
N‐heterocyclic carbenes (NHCs) function as “molecular scissors,” cleaving otherwise inert Sb═Sb bonds in distibenes to generate monomeric, zwitterionic stibinide species. These intermediates act as efficient stibinidene transfer reagents, granting access to a rare terminal cobalt–stibinidene complex.
Daniel Meleschko +7 more
wiley +2 more sources
Agrochemical residues and food safety: In-depth in silico assessment of the degradation mechanism of chlorpyrifos-oxon by niobium dioxide (NbO₂), a naturally occurring and cost-effective mineral. [PDF]
Braga LS, Aquino AJA, Ramalho TC.
europepmc +1 more source
SO2 Transfer Enabled by an Easy‐to‐Handle Ionic Liquid
Best of both worlds: The ionic liquid [NEt3Me][Cl(SO2)n] unites the atom economy and low cost of sulfur dioxide with the safety and applicability of common surrogates, streamlining SO2 transfer to access to 3‐sulfolenes, sulfonamides, and SuFEx reagents.
Johanna S. Sturm +11 more
wiley +1 more source
Normobaric Hyperoxia Therapy in Treating Stroke
Yanli Duan,1,* Xiangyu Li,2,* Song Han,1 Jingwei Guan,1 Zhiying Chen,3 Weili Li,4 Ran Meng,5 Jiayue Ding1 1Department of Neurology, Tianjin Medical University General Hospital, Tianjin, People’s Republic of China; 2Department of Neurology,
Duan Y +7 more
doaj
Truncation of Samroiyotmycin: Tailored seco‐Acids as Novel Antimalaria Compounds
Six truncated samroiyotmycin‐derived antimalarials were synthesized by replacing the tosyloxazole unit with electron‐deficient aryl groups. The most active seco‐acid with EWG = 2 × CF3 outperformed the natural product SamA. Its enhanced activity supports a donor–acceptor interaction involving the electron‐poor aryl unit, consistent with inhibition of ...
Anton Czuczkowski +10 more
wiley +1 more source
Preparation and Chlorination of NbO<SUB>2</SUB>, NbO and NbC
Riichi BABA, Koji IMAGAWA, Shunji KIUCHI
openaire +2 more sources
Borylcyclopropanes: Synthetic Strategies and Applications
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley +2 more sources
Acetaminophen toxicity: Patterns of liver injury, effects on hospital length of stay, and the need for inpatient psychiatric care. [PDF]
Ozturk NB, Da BL, Ezaz G, Schiano TD.
europepmc +1 more source
Time‐Dependent Oxidation and Scale Evolution of a Wrought Co/Ni‐Based Superalloy
This study shows how a new wrought Co/Ni‐based superalloy resists oxidation at 800 ∘$^\circ$C. The oxide scale changes from rough, fast‐growing spinel to a dense, protective chromia–alumina layer. Atom probe analysis reveals tiny refractory‐rich bubbles at the interface that mark the transition to long‐term, diffusion‐controlled protection ...
Cameron Crabb +6 more
wiley +1 more source

