Results 131 to 140 of about 3,800,436 (239)

Synthesis and Characterization of a Cerium(IV) Coordination Polymer Containing Isonicotinic Acid Zwitterions

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
The new coordination polymer [Ce4O2(OH)2(NO3)2(C6H5NO2)8](NO3)8 is reported. It was discovered during a ligand screening experiment. Its crystallization was studied in situ via powder X‐ray diffraction and X‐ray absorption near‐edge structure spectroscopy.
Niklas Ruser   +9 more
wiley   +1 more source

Structural Complexity From Powder X‐Ray Diffraction Data: Sr25[Mn42N50]: A New Member in the Family of Two‐Dimensional Intergrowth Nitridometalates

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
Sr25[Mn42N50] represents a new member in the family of layered nitridomanganates with complex crystal structures built up by 2D intergrowth – tiling at its best. The new compound Sr25[Mn42N50] (space group P 3¯, Pearson code hP117, a = 17.9756(7) Å, c = 5.7935(2) Å) represents a new member in the family of layered nitridomanganates with complex crystal
Alexander Ovchinnikov   +5 more
wiley   +1 more source

From Heterocubane Units to Extended Networks: Synthesis, Structure, and Optical Properties of Pb9O2I8(CN2)3 and Pb16O5I14(CN2)4

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
Two air‐stable, photoluminescent lead oxide iodide carbodiimides, Pb9O2I8(CN2)3 and Pb16O5I14(CN2)4, were synthesized via solid‐state methods and structurally characterized, revealing heterocubane‐type units interconnected by iodide and (NCN)2‐ ligands.
Albert T. Schwarz   +4 more
wiley   +1 more source

Synthesis, Structure, and Eu3+‐Activated Photoluminescence of the Mixed‐Anion Carbodiimide NaLa2F3(CN2)2

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
NaLa2F3(CN2)2 forms via solid‐state metathesis of LaF3 and Na2(CN2) at 550°C and remains stable under ambient air and humidity. The structure is based on [La(NCN)5F4] polyhedra with interstitial Na+; revealing an unconventional red emission when doped with Eu3+.
Albert T. Schwarz   +4 more
wiley   +1 more source

Spatial distribution of 6s2 lone electron pair in Pb4Na(PO4)3 and stereochemical activity of the 6s2 electron cloud in lead‐bearing apatites

open access: yesActa Crystallographica Section B, EarlyView.
In lacunary apatite structure‐type Pb4Na(PO4)3, residual density attributable to the deformed 6s2 electron cloud is found in the vicinity of A2‐site Pb2+ on regular A2 triangle normal to c. Systematic comparison on the size of the A2 triangle with other apatite‐type compounds indicates limited stereochemical activity of the orbital.Single crystals of ...
Kotomi Hirano, Hiroki Okudera
wiley   +1 more source

CRYSP: construction and visualization of crystal shapes in natural habits and on planar substrates

open access: yesActa Crystallographica Section B, EarlyView.
CRYSP is a software tool for the construction and visualization of crystal shapes in both natural habits and on planar substrates. It also supports morphologies associated with non‐crystallographic point groups.CRYSP has been developed as a crystallographic tool for the construction and visualization of crystal shapes. The input parameters for software
Xing-Zhong Li
wiley   +1 more source

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