Results 71 to 80 of about 14,736 (198)

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open access: yesNetwork Biology
Network Biology ISSN 2220-8879
Network Biology (ISSN 2220-8879)
doaj  

Contra‐Diffusion Engineering of Single‐Atom Catalytic Interlayers Enables Reversible Sulfur Redox Chemistry

open access: yesAngewandte Chemie International Edition, EarlyView.
A contra‐diffusion strategy is introduced to grow uniformly distributed Co–Nx single‐atom catalysts (CoSAs) within a carbonized aramid nanofiber (CANF) interlayer. The resulting CD‐CANF enables efficient polysulfide regulation, low metal loading, and exceptional long‐term cycling stability in lithium–sulfur batteries. ABSTRACT Achieving durable lithium–
Yan‐Jhang Chen   +8 more
wiley   +1 more source

(NH4)2[Tc2O2(S2O7)4]: An Unexpected Technetium(V)‐Sulfate From the Reaction of (NH4)(TcO4) With SO3

open access: yesChemistry – A European Journal, EarlyView.
The reaction of the radioactive pertechnetate (99TcO4)− with the oxidizer SO3 leads to blue crystals of (NH4)2[Tc2O2(S2O7)4]. The complex dimeric [Tc2O2(S2O7)4]2− anion exhibits the technetium in the oxidation state V, showing that reduction occurs during the reaction.
Stefan Sutorius   +5 more
wiley   +1 more source

Influence of Carboxylate Ligand Variation on Structure, Magnetic Exchange, and Magnetocaloric Performance in Hexanuclear Gd(III) Complexes

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT Hexanuclear cyclic Gd(III) coordination compounds are promising candidates for magnetic and magnetocaloric applications, yet systematic series remain rare due to synthetic challenges. We report the synthesis and characterization of five new complexes with the general formula [Gd(H3bt)(carboxylate)]6, employing four different carboxylate ...
Ondřej František Fellner   +7 more
wiley   +1 more source

Ladder‐Like Structural Architecture of Layered Magnetic A2.4 Cr8Te14 (A = Rb, Cs) Compounds by Self‐Flux Synthesis

open access: yesChemistry – A European Journal, EarlyView.
A2.4Cr8Te14$A_{2.4}{\rm Cr}_{8}{\rm Te}_{14}$ (A = Rb, Cs) compounds exhibit a layered, ladder‐like Cr‐Te framework uniting structural motives of hollandite‐like and delafossite‐like phases. Alkali atoms are situated both in the interlayer space and tunnels within the Cr8Te14${\rm Cr}_{8}{\rm Te}_{14}$ framework.
Kai D. Röseler   +2 more
wiley   +1 more source

Self-Assembly, Self-Folding, and Origami: Comparative Design Principles. [PDF]

open access: yesBiomimetics (Basel), 2022
Jungck JR   +3 more
europepmc   +1 more source

Precipitation of niobic acid from potassium niobate in sulphuric acid solution: A route to niobium oxide

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Graphical abstract illustrating the niobic acid precipitation process applied and the product obtained. Abstract This study investigates the precipitation of niobic acid (Nb2O5.nH2O) from potassium niobate solution with addition of sulphuric acid, and its subsequent thermal conversion into niobium oxide (Nb2O5). Thermodynamic modelling with PHREEQC and
Cássia R. Souza   +4 more
wiley   +1 more source

Tuning the Growth Pattern of Triangular Silver Nanoplates from Lateral to Vertical by Secondary Metal Addition

open access: yesChemPhysChem, Volume 26, Issue 6, March 15, 2025.
What happens, if in the synthesis of flat silver platelets, the slow deposition of silver along twinning faults is disturbed by the addition of a nobler metal? We have looked into it and found a way to fine‐tune the metal deposition in lateral and vertical direction.
Jonas Kluitmann   +3 more
wiley   +1 more source

Cobalt‐Free Single‐Crystal Cathodes for Next‐Generation Lithium‐Ion Batteries

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Cobalt‐free single‐crystal cathodes enhance lithium‐ion battery stability by mitigating fracture, degradation, and phase transitions. This review highlights Ni‐rich layered, Li‐Mn‐rich, spinel, and olivine frameworks, synthesis strategies enabling morphology and defect control, and structural tuning via doping and coatings, offering pathways toward ...
Srinivasan Alagar   +5 more
wiley   +1 more source

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