Results 161 to 170 of about 607 (217)
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Pyridinecarboxamidato−Nickel(II) Complexes
Organometallics, 2001The synthesis, characterization, and reactivity toward ethylene of pyridinecarboxamidato complexes of nickel are reported. These compounds are isoelectronic to α-iminocarboxamidato complexes, which are useful ethylene polymerization catalysts. Addition of a benzene solution containing N-phenyl-2-pyridinecarboxamide and B(C6F5)3 to bis(methallyl)nickel ...
Bun Yeoul Lee +2 more
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Nickel(II) Cyanoborates and Cyanoborate-Ligated Nickel(II) Complexes
Inorganic ChemistryNickel(II) cyanoborates Ni[BH2(CN)2]2·H2O (1b·H2O), Ni[BH(CN)3]2·0.5H2O (1c·0.5H2O), and Ni[B(CN)4]2·0.5H2O (1d·0.5H2O) were synthesized, and their reactivity with respect to dppeO2 (=1,2-bis-(diphenylphosphinoethane dioxide)), pyNO (=pyridine-N-oxide), dppe (=1,2-bis-(diphenylphosphinoethane), and DMSO (=dimethyl sulfoxide) was examined.
Martin S. Luff +4 more
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An Aminobenzyldioxocyclam Nickel(II) Complex
Acta Crystallographica Section C Crystal Structure Communications, 1995The structure was solved by the Patterson method and suc- cessive Fourier electron density difference maps, and refined by full-matrix least-squares procedures with anisotropic tem- perature factors for all non-H atoms. The positions of all H atoms were generated geometrically in the final stages of re- finement.
J. K. Moran +2 more
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Hydrogensulphito Complexes of Nickel (II)
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1989Abstract The reactions of Na2S2O5 with [Ni2L4Cl2]Cl2, where L = 1, 2-diaminoethane or 1, 2-diaminopropane, yielded hydrogensulphito, [NiL(HSO3)2], complexes. The IR and visible spectra and the magnetic moments of the complexes indicated that they are hexacoordinated where the HSO3 groups act as bidentate chelate ligands.
Kamal A.R. Salib, Saied M. El-sayed
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Highly Distorted Bismuth–Nickel(II) Complex
Inorganic Chemistry, 2023The synthesis and characterization of a series of nickel complexes bearing a bismuth-containing pincer ligand are presented herein. In particular, synthesis of a 4-coordinate Bi-Ni(II) complex allows the influence of bismuth on a d8 Ni(II) ion to be investigated. A trigonal-bipyramidal complex, (BiP2)Ni(PPh) (1), possessing an anionic bismuth donor was
Alexander C. Brannan +3 more
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Stereochemical versatility of nickel(II). Nickel(II) complexes of cyclohexanone thiosemicarbazone
Transition Metal Chemistry, 1980Using cyclohexanone thiosemicarbazone as ligand (L), nickel(II) complexes, NiL2X2 · nH2O, have been prepared for various anions. Their properties are as follows: X = Cl, green paramagnetic, 5-coordinate; X = Br dimorphous; green, diamagnetic, square-red; paramagnetic, possibly square pyramidyl; X = nitrate, dimorphous-anhydrous, red, diamagnetic ...
Sulekh Chandra +2 more
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A tetrahedral complex of cobalt(II) and nickel(II)
Inorganic and Nuclear Chemistry Letters, 1974Abstract The compound described is a tetrahedral complex of nickel(II) in which isomorphous replacement by cobalt(II) occurs. Nitrogen is the donor atom in this compound.
A.W. Downs, B.A. Götz, A.E. McCarthy
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D-galactosamine complexes with copper(II), nickel(II), and cobalt(II)
Journal of Inorganic Biochemistry, 1988The potentiometric and spectroscopic methods were applied to describe the equilibria for the Cu(II), Ni(II), and Co(II), D-galactosamine solutions. The stability constants, the spectral data, and the results obtained earlier precisely defined the binding ability of the aminosugars.
RADOMSKA B +4 more
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Complexes of nickel(II) and palladium(II) with thiobenzamide
Transition Metal Chemistry, 1979The electronic and vibrational spectra of NiII and PdII complexes with thiobenzamide, L, are discussed. L acts as a sulphur donor ligand. The PdII compounds and (NiL4)(ClO4)2 are square planar. PdL2Cl2 has acis-structure, while PdL2X2 (X=Br or I) istrans; NiL4Cl2 istrans-octahedral. The i.r. bands due toν(M.S) andν(MX) have been assigned. The influence
Andr� J. Aarts +2 more
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2007
Cobalt(II) complex with 6-hydroxypicolinic acid and 4-picoline was synthesized. Two pseudopolymorphs of nickel(II) complex with 6-methylpicolinic acid were also prepared. The molecular and crystal structures of prepared compounds were determined.
Kukovec, Boris-Marko +2 more
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Cobalt(II) complex with 6-hydroxypicolinic acid and 4-picoline was synthesized. Two pseudopolymorphs of nickel(II) complex with 6-methylpicolinic acid were also prepared. The molecular and crystal structures of prepared compounds were determined.
Kukovec, Boris-Marko +2 more
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