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Oxidation of niobium aluminide NbAl3
Materials Science and Engineering: A, 1989Abstract The oxidation of the intermetallic compound NbAl 3 and of materials with some excess aluminium (NbAl 3 + Al) was investigated at temperatures between 650 and 1200 °C in He − 133.3 mbar O 2 . At temperatures between 1000 and 1200 °C, the NbAl 3 single phase shows a quasi-linear oxidation rate caused by cracking and spallation of the ...
M Steinhorst, H.J Grabke
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The Microtopography of Oxide Films on Niobium
Journal of The Electrochemical Society, 1958An electron microscopic study of the oxide films formed on niobium permits the apparently anomalous oxidation rate behavior of niobium to be explained in terms of the formation of small, blister-like cracks in the oxide film. An oxidation model, based on the idea that an oxidation process which is maintained by interstitial-anion or anion-vacancy ...
J. V. Cathcart +2 more
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Thermodynamic Properties of Niobium Oxides
Journal of Chemical & Engineering Data, 2010Thermodynamic properties of three oxides of niobium have been measured using solid state electrochemical cells incorporating yttria-doped thoria (YDT) as the electrolyte in the temperature range T = (1000 to 1300) K. The standard Gibbs energies of formation of NbO, NbO2, and NbO2.422 from the elements can be expressed as: Delta(f)G(NbO)(o) +/- 547/J ...
Jacob, KT +3 more
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Effect of boronizing on the oxidation of niobium
International Journal of Refractory Metals and Hard Materials, 2013Abstract Niobium (Nb) and its alloys are used in various industrial applications including metal processing, nuclear power generation and manufacturing of metallic superconductors and rocket nozzles. Although it is resistant to corrosion in several liquid media, Nb has a high oxidation rate in environments such as air at temperatures above 400 °C. In
Ozyigit, M. B. +3 more
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The oxidation of niobium single crystals
Acta Metallurgica, 1969Abstract Single crystals of niobium in the form of 1 4 -in. dia. spheres have been oxidised in dry oxygen at approximately 400 torr pressure in the temperature range 550–925°C. The results indicate that suboxide platelets are present at temperatures below 600°C, and produce lines of pores in the scale, as reported for tantalum. The lines of pores
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EELS Investigations of Reference Niobium Oxides and Anodically Grown Niobium Oxide Layers
Microscopy and Microanalysis, 2007Bach, D. +4 more
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Application of niobium oxides as catalysts
Catalysis Today, 1990Abstract Characteristics of niobium oxides as a promoter of various catalysts, a catalyst support, and a unique solid acid catalyst is reviewed. The pronounced effects as a promoter and a support of catalysts for diversified reactions are demonstrated and the strongly acidic nature of hydrated niobium oxide and its application as an unusual ...
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Methods to partially reduce a niobium metal oxide and oxygen reduced niobium oxides
2002KIMMEL JONATHON L +2 more
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