Homochiral Cu(I) cyanide complexes based on 2,2’‐bis(diphenylphosphino)‐1,1’‐binaphthyl (BINAP) form melt‐quenched and desolvation‐derived metal–organic glasses that exhibit circularly polarized thermally activated delayed fluorescence (TADF) at room temperature, enabling processable chiroptical materials.
Zeyu Fan +5 more
wiley +2 more sources
Chemoselective C-Terminal Activation Platform for Direct Conversion of Native Linear Peptides into Thiazoline/Thiazole Macrocycles. [PDF]
Le BQG, Kwon M, Raj M.
europepmc +1 more source
Expanding the Chemoproteomic Toolkit to Asparagine and Glutamine. [PDF]
Emenike B +6 more
europepmc +1 more source
Glycine molecules induce a unique crystal packing into a supramolecular one‐dimensional columnar structure of octacyanidotungstates, which exhibits exceptionally strong antiferromagnetic superexchange interactions of J = −42.41(2) K between adjacent octacyanidotungstate units.
Tatsuya Konishi +8 more
wiley +2 more sources
Rhodium-Catalyzed Desymmetric Addition of Boronic Acids to Malononitriles. [PDF]
Zhang M +5 more
europepmc +1 more source
Biocatalytic Synthesis of Isoxazolines Enabled by Cryptic Nitrile Oxide Formation by a Vanadium-Dependent Chloroperoxidase. [PDF]
Sharma M, Biegasiewicz KF.
europepmc +1 more source
Unlocking the Silent Proteome: Chemoselective Asn/Gln Activation for Multidimensional Protein Diversification. [PDF]
Emenike B +7 more
europepmc +1 more source
Aziridinierung eines einzelnen Kohlenstoffatoms in Alkenen mittels Energietransferkatalyse
Im Gegensatz zur traditionellen Alken‐Aziridinierung über (formalen) Nitren‐Transfer berichten wir hier über eine Strategie zur intermolekularen Aziridinierung eines einzelnen Alken‐Kohlenstoffatoms bei zusätzlicher Funktionalisierung der anderen Position. Durch Energietransfer‐ (EnT‐)Katalyse werden Alkenylboronate und ‐silane in reaktive Intermediate
Fritz Paulus +7 more
wiley +1 more source
Asymmetric Decarboxylative Protonation and Deuteration of Cyanoacetic Acids Using an Organometallic Proton Shuttle. [PDF]
Zheng WF +5 more
europepmc +1 more source

