Results 171 to 180 of about 60,817 (284)

The Challenging P‐Alkylation of Aromatic Phosphorus Heterocycles and Follow‐Up Reactions

ChemistryEurope, EarlyView.
P‐alkylation of λ3σ2‐phosphinines is hindered by weak nucleophilicity and scarce synthetic access, previously requiring multistep routes or extreme electrophiles. A direct ambient‐condition method is reported using 3,5‐bis(trimethylsilyl)‐phosphinine/B(C6F5)3 with esters or iso(thio)cyanates to generate stable 1‐R‐phosphininium salts.
Samantha Frank, Ádám Horváth, Duy Nguyen, Moritz J. Ernst, Simon Steinhauer, Zoltán Benkő, Christian Müller   +6 more
wiley   +1 more source

Modular Access to Quaternary α‑Cyano Carbonyl Compounds via NiH Catalysis. [PDF]

JACS Au
Lee Y, Jung Y, Choo S, Shin K.
europepmc   +1 more source

Skeletal Editing from Pyridine to Aniline via C‐Insertion and N‐Isomerization

ChemistryEurope, EarlyView.
A concise protocol is presented that converts pyridines into anilines by externalizing the original pyridine nitrogen at either the "ipso" or "ortho" position, which results in para or meta‐primary aniline products. A key carbene‐insertion step precedes nitrogen migration, preserving both ring size and overall structure.
Yun Luo, Jing Dai, Yongchang Wei, Chang Min   +3 more
wiley   +1 more source

Investigating the potent antibacterial, antibiofilm, antidiabetic, and antioxidant activities of biosynthesized iron oxide nanoparticles: recyclable catalyst for ammoxidation of aromatic aldehydes. [PDF]

RSC Adv
Das AK, Misra A, Ali MS, Saikh MS, Dhibar S, Banerjee KK, Ghatak G, Mal D, Shit M, Biswas S.   +9 more
europepmc   +1 more source

Regulating Interfacial Hydrogen‐Bonding Connectivity by Oxygen Vacancies‐Driven [Fe(CN)6]3− Coordination for Boosting Hydrogen Peroxide Electrosynthesis

Carbon Energy, EarlyView.
ABSTRACT The inherent hydroxide‐rich (OH⁻) environment in alkaline media facilitates the two‐electron oxygen reduction reaction (2e−ORR). However, the strong interaction between alkali metal cations and solvated water molecules significantly reduces the connectivity of the hydrogen bond network within the alkaline electric double layer, thereby ...
Kaiming Li, Ben Huang, Aihao Xu, Kai Nie, Xianhai Bai, Qian Ning, Guodong Wang, Shiming Qiu, Huibing He, Yang Ren, Jing Xu, Xucai Yin   +11 more
wiley   +1 more source

Silylative Amide to Nitrile Conversion Mediated by Simple Lanthanide-Organoamides: Scope and Mechanism. [PDF]

Angew Chem Int Ed Engl
Feng Z, Lai Q, Wang Y, Motta A, Kratish Y, Marks TJ.   +5 more
europepmc   +1 more source

Three‐Layer‐Structured Garnet‐Dominant Composite Solid Electrolyte for Solid‐State Batteries

Carbon Energy, EarlyView.
The three‐layer‐structured garnet‐dominant composite solid electrolyte (GD‐CSE) is designed for solid‐state batteries. The GD‐CSE is composed of over 80 wt. % contents of LGLZO. This three‐layer CSE has high ionic conductivity and high potential stability.
Wooyoung Lee, Jongmin Lee, Seohye Jeon, Joonsoo Kim, Ji Haeng Yu, Kyong Sik Yun, Jung Hyun Lee, Jungjoon Yoo, Tae Woo Kim, Sinho Choi, Yu‐Jin Han, Sang‐Hoon Park, Boyun Jang, Daeil Kim   +13 more
wiley   +1 more source

Headspace Volatile Profile of Fresh-Cut Broccoli Raab in PET Packaging as Affected by Microperforation. [PDF]

Foods
Saleem A, Pati S, Rosiello G, Amodio ML, Colelli G.   +4 more
europepmc   +1 more source

Multifunctional Design of Solid Polymer Electrolytes: Paving the Way for High‐Performance All‐Solid‐State Batteries

Carbon Energy, EarlyView.
This review provides a comprehensive and systematic overview of the multifunctional design strategies for solid polymer electrolytes (SPEs), a pivotal component for enabling high‐performance all‐solid‐state batteries (ASSBs). It begins with a detailed classification of SPE systems and elaborates on their respective molecular design principles. The work
Bin Man, Yuzhen Zhao, Bo Fu, Yulong Zeng, Yinwen Chen, Qingrui Liu, Wenjing Luo, Xin Li, Xuewei Li, Zikang Zhang, Yun Zheng, Sijie Liu   +11 more
wiley   +1 more source

Enantioselective Radical Hydrocyanoalkylation of Alkenes via Photoenzymatic Catalysis. [PDF]

JACS Au
Wu D, Sun Z, Wang S, Yang J, He J, Lei X.   +5 more
europepmc   +1 more source