Insertion of CO<sub>2</sub>, Isocyanates, and Acetonitrile into the P-Si Bond of a Silyl-Substituted <i>N</i>‑Heterocyclic Carbene Phosphinidene. [PDF]
Hochholzer A +3 more
europepmc +1 more source
A sustainable synthesis of cobalt phthalocyanine (CoPc) using low‐impact solvents yields high‐performance electrocatalysts with reduced waste (E‐factor 18.6). When integrated into gas diffusion electrodes, CoPc achieves up to 12% Faradays efficiency for CO2‐to‐methanol and 65% CO2‐to‐CO conversion, aligning with state‐of‐the‐art materials and enabling ...
Gloria Zanotti +10 more
wiley +1 more source
Versatile Palladium‐Catalyzed C‐H Arylation of Fluoroarenes with 2‐Chloropyridine Derivatives
Direct C─H arylation of fluoroarenes with 2‐chloropyridines is enabled by a simple Pd/SPhos system in isopropyl acetate. The method uses inexpensive reactants and shows broad scope and high yields. DFT computations explain reactivity and selectivity.
Federico Belnome +6 more
wiley +1 more source
Dual-atom Rh-Co catalysts for synergistically boosting nitrile hydrogenation. [PDF]
Chen J +9 more
europepmc +1 more source
Pharmaceuticals Made with Hydrogen: A Sustainable and Efficient Approach Using Flow Synthesis
We demonstrate a sustainable strategy for pharmaceutical manufacturing by combining hydrogen, heterogeneous catalysis, and continuous flow synthesis. The development of novel catalysts and their application in a multi‐step synthesis of donepezil enabled a highly productive process with no intermediate purification.
Shū Kobayashi, Haruro Ishitani
wiley +1 more source
Modular Access to Quaternary α‑Cyano Carbonyl Compounds via NiH Catalysis. [PDF]
Lee Y, Jung Y, Choo S, Shin K.
europepmc +1 more source
Investigating the potent antibacterial, antibiofilm, antidiabetic, and antioxidant activities of biosynthesized iron oxide nanoparticles: recyclable catalyst for ammoxidation of aromatic aldehydes. [PDF]
Das AK +9 more
europepmc +1 more source
Silylative Amide to Nitrile Conversion Mediated by Simple Lanthanide-Organoamides: Scope and Mechanism. [PDF]
Feng Z +5 more
europepmc +1 more source
Enantioselective Radical Hydrocyanoalkylation of Alkenes via Photoenzymatic Catalysis. [PDF]
Wu D +5 more
europepmc +1 more source

