Angewandte Chemie, EarlyView.Anionic high‐spin iron(II) imido complexes are catalysts for the hydrogen isotope exchange (HIE) reaction with pyridine as the substrate. The alkali metal counter‐cation plays critical roles in activating the substrate and facilitating deuteration. These complexes catalyze site‐selective α‐, α,β,γ‐, and β,γ‐deuteration of pyridine, where the counter ...
Bin Feng +6 more
wiley +2 more sources
On-complex three-component cascade reactions involving phosphorescent cyclometalated Ir(iii) chloro-isocyanide complexes, nitriles, and propylamine. [PDF]
Chem SciPhan SNT, Dang VQ, Teets TS.
europepmc +1 more source
Computational Experiments Probing the Adaptability of the [NCCH<sub>2</sub>]<sup>-</sup> Electronic Structure to Various Bonding Environments. [PDF]
ChemphyschemRio J, Brière JF, Gérard H.
europepmc +1 more source
TfOH-Promoted Cascade Reaction of Nitriles and 1,5-Enynes: An Efficient Route to Amido-Functionalized Fluorenes. [PDF]
J Org ChemGore BS, Liu WJ, Pan LW, Li CH, Wang JJ.
europepmc +1 more source
Angewandte Chemie, EarlyView.Gold recycling from electronic waste using porous materials is an emerging concept to reduce the environmental impact of gold mining. In this work, we report the synthesis of a highly porous phenazine‐derived tetraoxa[8]circulene polymer and its utilization in gold capture and heterogeneous catalysis.
Patrick W. Fritz +4 more
wiley +2 more sources
Isocyanides Versus Nitriles: Divergent Hydrogen Bonding Behavior Driven by the Balance Between Dispersive and Electrostatic Forces. [PDF]
ChemphyschemKanzow A, Suhm MA, Bödecker M.
europepmc +1 more source
Iron‐Photocatalyzed C(sp3)–H Phosphonylation of Alkanes
Angewandte Chemie, EarlyView.Alkyl phosphonates are valuable motifs that can be prepared by phosphonylations of various common functional groups. However, direct phosphonylations of C(sp3)–H bonds are limited to activated positions. Herein, we report an iron‐photocatalyzed phosphonylation of unactivated C(sp3)–H bonds using a novel phosphite radical trap, which is equipped with an
Ya Dong +6 more
wiley +2 more sources
NiMoO<sub>4</sub> With High Oxidation States for Efficient Electrooxidation of Amines to Nitriles. [PDF]
Exploration (Beijing)Chen H +5 more
europepmc +1 more source
Angewandte Chemie, EarlyView.The use of transition‐metal catalysts and design of chiral ligands have allowed chemists to access highly functionalized benzofused 5‐ and 6‐ membered rings in high yield and enantioselectivity. A common strategy used relies on an intermolecular carbometalation across alkynes and olefins, usually followed by a subsequent intramolecular carbometalation.
Clara Jans +3 more
wiley +2 more sources
Efficient, Functional Group-Tolerant, and Catalyst-Free Nitrile Formation from Aldehydes. [PDF]
ChemistryAydonat S, Campagna D, Göstl R.
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