Results 161 to 170 of about 272,370 (302)

Unlocking the Functionalization and Reactivity of Ethylene Bridges in [2.2]Paracyclophanes: Strategies and Challenges

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Bridging the gap. Beyond deck functionalization, the ethylene bridges of [2.2]paracyclophanes offer a largely unexploited reactivity landscape. This review showcases strategies to functionalize these bridges and leverage them to build novel cyclophane architectures.
Rongyu Sun   +3 more
wiley   +1 more source

Dibenzosuberene‐Winged Polycyclic Aromatic Hydrocarbons

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The twisted acene 8, which features two dibenzosuberene “wings”, was prepared by the addition of a crowded aryne to a similarly “winged” cyclopentadienone. Compound 8 is chiral, and it has a high barrier to thermal racemization (ΔG‡rac = 36 kcal/mol), but it undergoes fast photochemical racemization even in ambient light.
Mingshu Xie   +3 more
wiley   +1 more source

Fast Reduction of Nitroalkenes Into Nitroalkanes Under Continuous‐Flow Chemical Conditions

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Flow chemical synthesis was employed for the reduction of nitroalkenes to the corresponding nitroalkanes using sodium borohydride as the reducing agent. The reaction proceeds in only 150 s, affording products from good‐to‐excellent yields (61–96%). Herein, we describe an efficient and rapid continuous‐flow reduction of nitroalkenes to nitroalkanes. The
Iqra Munir   +3 more
wiley   +1 more source

Validated RP‐HPLC–UV Method for the Quantitative Analysis and Stability Evaluation of Amoxicillin in Paediatric Gummy Tablets

open access: yesELECTROPHORESIS, EarlyView.
A validated RP‐HPLC–UV method was successfully applied for amoxicillin determination in gummy tablets. The method is useful for an accurate amoxicillin content determination in paediatric gummies and was applied to study the stability profile of the drug, evaluated over 6 months under storage conditions.
Samuele Bonafè   +7 more
wiley   +1 more source

Phosphate and fluoride removal options for Hanford high‐level waste sludge processing

open access: yesEnvironmental Progress &Sustainable Energy, EarlyView.
Abstract High‐phosphate and high‐fluoride sludges represent some of the most challenging waste streams within the Hanford High‐Level Waste (HLW) inventory due to solubility constraints, impacts on glass loading, and corrosion risks during vitrification.
A. M. Westesen   +4 more
wiley   +1 more source

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