Results 131 to 140 of about 25,395 (287)

Hydroquinone Oxidation by Redox‐active Guanidines and Thioguanidines: Faster Conversion to High‐Potential Than to Low‐Potential Quinones

Chemistry – A European Journal, EarlyView.
New redox‐active oligothioguanidines are developed and used in dehydrogenative P–P coupling reactions and hydroquinone oxidations. Tetrathioguanidino‐ and tetraguanidinobenzenes oxidize high‐potential halogenated hydroquinones faster than relatively low‐potential hydroquinone.
Ute Wild, Olaf Hübner, Sebastian Jaworski, Elisabeth Kaifer, Hans‐Jörg Himmel   +4 more
wiley   +1 more source

Dinuclear Copper(I) Complexes Featuring Metal–Metal Interactions and a μ2‐Bridging Phosphane With Additional Olefinic Binding Sites

Chemistry – A European Journal, EarlyView.
A Cu2P triangle captured in a tetrapodal phosphane tris(olefin) ligand, where all binding forces are weak apart from the Cu─P interaction. ABSTRACT The molecule Ptrop3 contains in each trop unit (trop = dibenzo[a,d]cyclohepten‐5‐yl) a rigid central seven‐membered ring with an olefinic binding site making Ptrop3 potentially a tetradentate ligand ...
Zhongshu Li, Daniel Himmelbauer, Jan Oswald, Michael Wörle, René Verel, Zoltán Benkő, Hansjörg Grützmacher   +6 more
wiley   +1 more source

The Role of Iron‐Hyponitrite Intermediates in Biology and Insights From Synthetic Model Complexes

Chemistry – A European Journal, EarlyView.
Despite the difference in active site architecture, NO reduction by different NOR enzymes is expected to be linked by a common intermediate: hyponitrite (N2O22−). However, experimentally, very little is known about the coordination chemistry of iron with hyponitrite and the expected Fe‐hyponitrite intermediates.
Michael O. Lengel, Nicolai Lehnert
wiley   +1 more source

Successive Azide and DNA Functionalization for Reversible and Controlled Association of Single‐Wall Carbon Nanotubes

Chemistry – A European Journal, EarlyView.
A newly synthesized bifunctional azide—diazonium linker allows robust one‐step introduction of azido groups to single‐wall carbon nanotubes. Versatility of the azido groups as reactive handles is demonstrated by further derivatization with 6‐carboxyfluorescein and oligonucleotides.
Razieh Moosavi, Tharun K. Kotammagari, Pia Damlin, Mikko Salomäki, Mika Lastusaari, Han Li, Tuomas Lönnberg   +6 more
wiley   +1 more source

Linear and Two‐Dimensional Infrared Spectroscopy of the Multifunctional Vibrational Probe, 3‐(4‐Azidophenyl) Propiolonitrile. Deperturbing a Fermi Triad by Isotopic Substitution

ChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Linear infrared spectroscopy combined with isotope labeling and density functional theory unravels the origin of a Fermi triad in a multifunctional vibrational chromophore. Ultrafast 2DIR‐spectroscopy reports directly on the dynamics and the intramolecular vibrational energy flow pathways in the isotopically deperturbed system. Abstract Infrared probes
Claudia Gräve, Jörg Lindner, Stefan Flesch, Luis I. Domenianni, Peter Vöhringer   +4 more
wiley   +1 more source

Biotechnology of final purification water from phenolic compounds and nitrites

, 2018
Визначено родовий склад мікробіоти води на різних етапах очищення води річки Дністер. Розроблена біотехнологія доочищення води від нітритів і фенольних сполук з застосуванням іммобілізованих клітин бактерій роду Bacillus.
Панджакідзе, Серго Теймуразович
core  

Silicone oil–based ferrofluid microrobots for versatile magnetic digital microfluidics

Droplet, EarlyView.
A magneto‐silicobotic system is a magnetic digital microfluidic platform that employs a silicone oil–based ferrofluid droplet as a chemically and biologically inert microrobot for the versatile manipulation of droplets and solid particles. Abstract Magnetic digital microfluidics offers a promising alternative to the dominant electrowetting‐based ...
Pu Liu, Leilei Chen, Yulei Fu, Wendong Wang   +3 more
wiley   +1 more source

Failure characteristics analysis of the inclined interlayer during water‐soluble cavity construction of underground salt caverns for large‐scale energy storage

Deep Underground Science and Engineering, EarlyView.
In the process of water‐soluble cavern construction of salt cavern energy storage, since the interlayer does not dissolve in water easily, sudden collapse will cause engineering accidents such as bending and damage of the inner tube of the cavern.
Zenghui Zhao, Tianyu Li, Qing Ma, Junlong Shang, Jiaze Du, Ruizhe He   +5 more
wiley   +1 more source

Stabilization of Pd Active Sites by Defective NaY Zeolite Framework for Enhanced Stability in Dimethyl Carbonate Synthesis

EcoEnergy, EarlyView.
A tailored‐defect strategy employing sequential high‐temperature calcination and acetylacetone treatment was developed to generate framework defects in NaY zeolite while preventing the formation of strong acid sites. These defects facilitate electron transfer from Pd to the zeolite framework and stabilize the Pd2+ active sites, thereby conferring ...
Chunzheng Wang, Rongyan Mei, Shicheng Yuan, Yida Zhou, Yipu Xu, Xianglong Meng, Longgang Tao, Shutao Xu, Hailing Guo, Svetlana Mintova   +9 more
wiley   +1 more source

Estimated dietary intake of nitrates, nitrites, and nitrosamines in U.S. women of child-bearing age

, 2009
Multiple N-nitroso compounds have been observed in animal studies to be both mutagenic and teratogenic in nature. Human exposure to N-nitroso compounds and their precursors, nitrates and nitrites, can occur through exogenous sources, such as diet ...
Griesenbeck, John Stephen
core