Results 31 to 40 of about 2,392 (185)

Bioinspired Porphyrin‐Based Catalysts From Temporospatial Confined Frameworks for Ultrafast Removal of Sulfaclozine

open access: yesAdvanced Science, EarlyView.
We report the rational design of artificial photocatalysts with asymmetrically coordinated dual‐metal centers and a tailored microenvironment, broadly applicable strategy is established for the synthesis of multivariate zirconium‐based metal–organic frameworks, offering a platform for precisely tuning active‐site configurations to optimize ...
Yuxin Lu   +11 more
wiley   +1 more source

N,N-Dimethylation of nitrobenzenes with CO2 and water by electrocatalysis

open access: yes, 2017
We have developed a strategy for the synthesis of N,N-dimethylanilines by the N,N-dimethylation of nitrobenzenes with CO2 using H2O as the hydrogen source.
Buxing Han   +6 more
core   +1 more source

4-Substituted 1-chloo-2-nitrobenzenes: Structure-activity relationships and extension of the subrate model of rat glutathione S-transferase 4-4.

open access: yes, 1997
In the present study, eleven 4-substituted 1-chloro-2-nitrobenzenes were tested for their GSH conjugation capacity when catalyzed by base or rat glutathione S-transferase (GST) 4-4.
Bijlo, G.J.   +11 more
core   +1 more source

Direct Photochemical Route for Amine- and Catalyst-Free Synthesis of Azoxybenzene and Functional Azoxy Derivatives via Accessible Nitroarene Homocoupling under Ambient Conditions [PDF]

open access: yes, 2022
We report on a direct photochemical method for the one-pot, catalyst- and additive-free synthesis of azoxybenzene and substituted azoxy derivatives from nitrobenzene building blocks.
Gregory, Hodgson   +7 more
core   +2 more sources

Sacrificial anode Fered–Fenton process for the degradation of a model naphthenic acid in high‐salinity water

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Fered–Fenton treatment of saline produced water: generation of reactive oxygen species and enhanced degradation of cyclohexane carboxylic acid through in‐situ electrochemical Fenton reactions. Abstract Offshore oilfield produced water (OPW) is a highly complex and hypersaline effluent from oil and gas extraction industry.
Daniela Gier Della Rocca   +7 more
wiley   +1 more source

Carbon‐Supported Catalytic Systems Assembled by π–π Interactions

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
This review explores the noncovalent immobilization of organic and organometallic catalysts on carbonaceous supports through π–π interactions, highlighting its potential to enhance catalyst recovery, recyclability, and the sustainability of organic synthesis.
Chloé Jamalkhan   +8 more
wiley   +1 more source

Frontiers in transition‐metal single‐atom electrocatalysts: Design tactics, mechanistic regulation, and electrochemical sensing technologies

open access: yesInfoMat, EarlyView.
This review offers an overview of recent advances in the fundamental properties, synthesis methods, and structural optimization of transition‐metal single‐atom electrocatalysts for electrochemical sensing. It also provides a comprehensive summary of the emerging applications in electrochemical assays based on these materials, along with key challenges ...
Yue Cao   +8 more
wiley   +1 more source

2‐Amino‐3H‐phenoxazin‐3‐one is a lead inhibitor of Cuscuta campestris early development: structure–activity relationships of o‐aminophenol‐derived allelochemicals

open access: yesPest Management Science, EarlyView.
Phenoxazinones caused differential types of phytotoxic effects in C. campestris early development. APO is a coherent lead inhibiting C. campestris germination and early seedling growth. Abstract BACKGROUND 2‐Amino‐3H‐phenoxazin‐3‐one (synonym: questiomycin A; abbreviated as APO or Phx‐3) is a naturally occurring phenoxazinone‐type allelochemical with ...
Cristina Díaz‐Franco   +5 more
wiley   +1 more source

Cross‐Scale Engineering of Single‐Atom Catalysts from Local Planar Coordination to Spatial Architectures

open access: yesSmall, EarlyView.
This Review presents a cross‐scale framework for single‐atom catalysts, spanning in‐plane and out‐of‐plane coordination; primary coordination, secondary‐sphere interactions, through‐space microenvironments and support interfaces; individual sites and macroscopic architectures; and static design and directed dynamic reconstruction.
Dazhi Yao   +4 more
wiley   +1 more source

A Serum‐Resistant Plasma Membrane Probe for Real‐Time Visualization of Pathogen‐Induced Epithelial Barrier Dysfunction

open access: yesSmall, EarlyView.
PM580 selectively activates at the plasma membrane while remaining minimally responsive to serum albumin, enabling serum‐compatible, surface‐confined imaging for 24 h, unlike conventional probes that rapidly internalize and lose membrane contrast.
Yujeong Choi   +12 more
wiley   +1 more source

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