Results 121 to 130 of about 27,351 (240)

Hyperpolarization of Pyridine 15N‐Oxide Molecular Probes Enabled by Parahydrogen

Angewandte Chemie, EarlyView.
Pyridine 15N‐oxides are introduced as motifs for hyperpolarization studies and biochemical applications are demonstrated. ABSTRACT Magnetic resonance (MR) is a powerful non‐invasive technique for probing structural, functional, and metabolic processes with high spatial and temporal resolution.
Ruhuai Mei, Lisa Maria Fries, Gonzalo Gabriel Rodriguez, Charlotte von Petersdorff‐Campen, Leander Konstantin May, Julius Frederik Matz, Sergey Korchak, Grysette Daher, Stefan Glöggler   +8 more
wiley   +2 more sources

Modulating Local Coordination in Single‐Atom Catalysts: From Fundamental Concepts to Emerging Breakthroughs in Electrocatalysis

Angewandte Chemie, EarlyView.
This review summarizes atomic‐level design strategies for single‐atom catalysts, emphasizing modulation of the local coordination environment, active‐site geometry, and metal‐support interactions to optimize catalytic activity and stability in electrocatalytic energy conversion applications.
Ashwani Kumar, Harun Tüysüz
wiley   +2 more sources

DETECTION OF NITROGEN FIXATION WITH ISOTOPIC NITROGEN

Journal of Biological Chemistry, 1943
R.H. Burris, F.J. Eppling, H.B. Wahlin, P.W. Wilson   +3 more
openaire   +1 more source

Direct Solar Power‐Driven Durable Ammonia Electrosynthesis From Nitrate Under Fluctuating Voltage Conditions

Angewandte Chemie, EarlyView.
Isolated Sn sites on Cu(111) induce a highly asymmetric charge distribution, which promotes water dissociation, accelerates key intermediate hydrogenation, and suppresses competing hydrogen evolution. As a result, SnCu111 delivers NH3 Faradaic efficiencies above 90% over an 800 mV potential window and enables stable direct solar power‐driven NH3 ...
Xiaokang Wang, Jiankun Li, Liyun Wu, Sirui Tang, Chuangwei Liu, Jianping Yang, Qilong Wu, Xiangdong Yao, Jun Chen   +8 more
wiley   +2 more sources

Exclusive Hydroformylation of Terminal Olefins: A Phosphorus‐Free Ruthenium System for the Selective Functionalization of Complex Mixtures

Angewandte Chemie, EarlyView.
Development of a phosphorus‐free Ru/DBU catalyst enabling highly chemo‐ and regioselective hydroformylation of terminal olefins, sparing internal double bonds. Optimization of reaction parameters, ligand effects, and substrate scope including industrial feedstocks was realized.
Mohamed Niyaz Vellala Syed Ali, Ida Ziccarelli, Dilver Peña Fuentes, Christoph Kubis, Robert Franke, Ralf Jackstell, Matthias Beller   +6 more
wiley   +2 more sources

Generation of the Camptothecin Scaffold by a Flavin‐Catalyzed Photooxidative Skeletal Reorganization

Angewandte Chemie, EarlyView.
The biosynthetic pathway of the anticancer drug precursor camptothecin involves an enigmatic skeletal reorganization from a 6/5/6 tetrahydro‐β‐carboline to a 6/6/5 pyrroloquinoline ring system. Here, we show that this transformation can be achieved by photooxidation with flavin cofactors, such as flavin mononucleotide (FMN) as catalysts.
Shenyu Liu, Zeliang Zhang, Benedikt Seligmann, Van Hung Bui, Tuan‐Anh Minh Nguyen, Thu‐Thuy T. Dang, Jakob Franke   +6 more
wiley   +2 more sources

Author Correction: Identification of fire severity in peat deposits using carbon and nitrogen isotopes. [PDF]

Sci Rep
Patria AA, Obrochta SP, Miyajima T, Behrens BC, Anggara F, Miyairi Y, Yokohama Y.   +6 more
europepmc   +1 more source

The application of stable carbon and nitrogen isotopes to assess the feeding ecology of long-finned pilot whales (Globicephala melas) in Scotland. [PDF]

PLoS One
Kebke AS, Plint T, Canseco JA, Davison NJ, Ten Doeschate MTI, Hooker SK, Magill CR, Monteiro SS, McGill R, Newton J, Trueman C, Brownlow A.   +11 more
europepmc   +1 more source

Stable carbon and nitrogen isotopes in kukui (Aleurites moluccanus) endocarp along rainfall and elevation gradients: Archaeological implications. [PDF]

PLoS One, 2018
Lincoln NK, McCoy MD, Ladefoged TN.
europepmc   +1 more source

Coupled Fe3O4‐Cluster Precipitates and Single Fe‐Atom Catalysts Can Boost Oxygen Reduction via Concomitantly Accelerated Water Dissociation

Angewandte Chemie, EarlyView.
Fe3O4 clusters can be precipitated onto Fe–N–C SACs through a residual‐oxygen‐assisted precipitation approach. Compelling evidence, including operando spectroscopy and ab initio calculations, suggests that Fe3O4‐cluster precipitates not only induce asymmetric electronic structures of Fe‐N4 active center to optimize the OH* adsorption, but also ...
Cheng‐Kai Du, Xiongyi Liang, Fei‐Xiang Ma, Yutong Li, Zheng‐Qi Liu, Long Ma, Zeng Li, Liang Zhen, Yan Huang, Xiao Cheng Zeng, Cheng‐Yan Xu   +10 more
wiley   +2 more sources