Results 101 to 110 of about 1,241 (129)

Soil pH Amelioration Synergizes Carbon Accrual with Yield Gains Under Organic Substitution

Advanced Science, EarlyView.
Soil pH shifts towards neutrality in both acidic and alkaline soils under organic substitution. A global synthesis links pH amelioration to soil organic carbon accrual through enhanced microbial biomass after accounting for added organic carbon and its interaction with pH. This pH amelioration‐shared soil organic carbon accrual accounts for 5.1–8.6% of
Xunzhuo Dong, Yanzhong Yao, Bingbing Han, Yunyao Zhong, Benyi Li, Mengfei Li, Yunchao Dai, Zhaolei Li   +7 more
wiley   +1 more source

Molecular Details of RNA Interactions With FUS Condensates Altering Assembly, Dynamics, and Aggregation

Angewandte Chemie, EarlyView.
Using NMR and molecular simulations, we map how RNA engages FUS LC‐RGG1 within condensates through electrostatic, π‐stacking, and polar contacts. These multivalent RNA contacts help stabilize RNA within FUS condensates while also reshaping condensate composition and dynamics.
Tongyin Zheng, Kandarp A. Sojitra, Samara Cummings, Qizan Chen, Priyesh Mohanty, Jeetain Mittal, Nicolas L. Fawzi   +6 more
wiley   +2 more sources

Surface‐Engineered Ti3C2Tx MXene/Cu2O Photocathodes for Highly Selective Photoelectrocatalytic CO2 Reduction to Ethanol

Advanced Energy Materials, EarlyView.
Surface‐engineering Ti3C2Tx MXenes with an in situ‐grown TiO2 layer on the surface in combination with visible‐light‐absorbing Cu2O significantly enhances charge separation and carrier extraction while improving Cu2O resistance to photocorrosion. The resulting Cu2O/TiO2‐MXene photocathodes enable highly selective, solar‐driven ethanol production ...
Luis A. M. Carrascosa, Magdaléna Linková, Monika Remzová, Tomáš Hrbek, Pavla Eliášová   +4 more
wiley   +1 more source

Redox‐Modulated σ‐Bond Reactivity in a Radical‐Anion Dimer

Angewandte Chemie, EarlyView.
A radialene‐based radical anion σ‐dimer comprising an elongated C‐C bond exhibits orthogonal stimuli responsiveness. Homolytic cleavage of the dimer to the radical state is triggered by mechanical strain and high temperature. Dimer scission is also achieved via oxidation, resulting in formation of neutral radialenes.
Sushil Ranjan Bhatta, Jonathan H. Gillen, Amaya T. Jayaweera, Fuead Hasan, Diana P. Merenkov, Hai Zhao, Sepideh Asgari, Arthur H. Winter, Christopher M. Bejger   +8 more
wiley   +2 more sources

Surface‐Functionalized MXene for Enhanced Photocatalytic CO2 Reduction

Advanced Energy Materials, EarlyView.
Poly(catechol/p‐cresol)‐functionalized MXene (f‐MXene) enhances oxidation stability while preserving conductivity, enabling efficient interfacial electron transfer in a Cu/f‐MXene/reduced TiO2 photocatalyst. Strong Cu–f‐MXene synergy promotes CO2 activation and selective CH4 production, achieving a CH4 yield of 18.1 µmol g−1 (>200 × vs.
Dongyun Kim, Young Ho Park, Dong Gyu Lee, Kyuseok Lee, Junho Lee, Chaelin Shin, Jaeyoung Kim, B. Yamunasree, Soomin Han, Eunhee Gong, Hyeonjong Jeong, Min Gyu Kim, Chang‐Hee Cho, Seung Jun Lee, Soorathep Kheawhom, G. Murali, Tae Kyung Lee, Insik In, Su‐Il In   +18 more
wiley   +1 more source

Configurational Entropy and Compositional Effects in Fe‐Based Oxide 2D Sheets for Nitrate Electroreduction

Advanced Energy Materials, EarlyView.
FeCuCoMnZnOx integrates diverse heteroatomic bridge‐site environments and composition‐dependent electronic structures to promote nitrate activation and sequential hydrogenation toward ammonia, demonstrating that nitrate reduction reaction performance is governed by the combined effects of composition and local coordination rather than configurational ...
Muhammad Usman, Zhehao Sun, Yi‐Lun Chen, Kaili Liu, Xuechen Jing, Soshan Cheong, Zeno R. Ramadhan, Jiayi Chen, Shuwen Cheng, Ary Anggara Wibowo, Daniel Macdonald, Lucy Gloag, Nicholas Cox, Richard D. Tilley, Zongyou Yin   +14 more
wiley   +1 more source

Activating Triplet Excitons in COFs via Layer‐Bridging Co Single Atoms for Photocatalytic H2O2 Production and Tandem C─N Coupling

Angewandte Chemie, EarlyView.
This work demonstrates a layer‐bridging coordination strategy of Co single atoms in COFs that promotes the formation and utilization of triplet excited states. The introduction of Co single atoms induces pronounced energy‐level splitting and enhanced spin–orbit coupling, facilitating the generation of 1O2 and O2•– for efficient photocatalytic H2O2 ...
Guoen Tang, Jianjun Zhang, Guijie Liang, Jinfeng Zhang, Chuanbiao Bie, Jiaguo Yu, Hermenegildo García   +6 more
wiley   +2 more sources

Sonocatalytic carbon dioxide reduction for syngas production over surface‐roughened CuxO catalyst

AIChE Journal, EarlyView.
Abstract The transition to a carbon‐circular economy requires efficient technologies for converting CO2 into value‐added chemical feedstocks. Sonocatalytic CO2 conversion has recently emerged as a compelling approach to drive this conversion. Here, we report a surface‐roughened CuxO catalyst for sonocatalytic CO2 reduction in aqueous media, achieving a
Dong Xia, Yi Qin, Hessan Khalid, Yagya N. Regmi, Laurie A. King, James Kwan   +5 more
wiley   +1 more source

Unveiling the Complete Biosynthetic Pathway of Azacitidine: A Rare 1,3,5‐Triazine Nucleoside Derived From GTP

Angewandte Chemie, EarlyView.
The azacitidine biosynthetic gene cluster (aza BGC) was identified by the resistance‐gene‐guided comparative genomics method in Streptomyces mobaraensis IPIO2. The complete biosynthetic pathway of azacitidine, which follows a “base‐first‐then‐glycosylation” logic, was elucidated through in vivo and in vitro experiments.
Dan Wang, Qingxu Meng, Lingqi Hua, Mengjun Sun, Qianjin Kang, Min‐Juan Xu, Linquan Bai   +6 more
wiley   +2 more sources

Second‐Sphere Aromatic Substitutions That Tune H‐Atom Transfer Reactivity Observed for a Series of S = 1 Nonheme FeIV=O Complexes: An Enthalpy‐Entropy Compensation Effect

Angewandte Chemie, EarlyView.
A series of oxoiron(IV) complexes was synthesized to determine the impact of electronically tuned aromatic substitution in the secondary sphere of the ligand. Despite possessing identical electronic properties, they show significant differences in C─H oxidation reactions.
Abhishek Das, Jin Xiong, Victor G. Young Jr., Yisong Guo, Marcel Swart, Lawrence Que Jr.   +5 more
wiley   +2 more sources