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Nitroxide-Substituted Nitronyl Nitroxide and Iminonitroxide
Journal of the American Chemical Society, 2010We report on the highly compact nitroxide-substituted nitronyl nitroxide 1 and iminonitroxide 2; they have isoelectronic structures with trimethylenemethane. These diradicals are stable under aerated conditions at room temperature and have large positive exchange interactions: J/k(B) = +390 K (H = -2JS(1)(/)(2)·S(1/2)) for 1 and J/k(B) ≈ +550 K for 2.
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