Results 141 to 150 of about 88,113 (258)

Catalyst‐Free Selective Reduction of Nitrogen Dioxide to Nitric Oxide

open access: yesChemistry – A European Journal, EarlyView.
Common main group reductants selectively convert nitrogen dioxide to nitric oxide in a catalyst‐free manner. Computational studies suggest divergent reaction pathways depending on the reductant employed. Where boranes and silanes proceed via a two‐electron process, and hydrogen surrogates undergo stepwise one‐electron processes.
Awais W. Seyyad   +3 more
wiley   +1 more source

Exploring Calixarene‐Based Pseudorotaxane Architectures: Threading Ammonium Axles With an Exo‐Rim π‐Functionalized Calix[6]Arene Macrocycle

open access: yesChemistry – A European Journal, EarlyView.
This research presents a novel 1,4‐π‐functionalized calix[6]arene with enhanced interactions with dialkylammonium axles. We investigate threading behavior in CDCl3, highlighting how exo‐rim π‐functionalization affects binding affinity and stereoselectivity.
Veronica Iuliano   +7 more
wiley   +1 more source

Nitrooxylation in Organic Synthesis: From Classical Nitrate Ester Formation to Modern Catalytic Strategies

open access: yesChemistry – A European Journal, EarlyView.
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley   +1 more source

Acidity Scale in 1,2-Difluorobenzene. [PDF]

open access: yesACS Omega
Samin JP   +6 more
europepmc   +1 more source

Cross‐Dehydrogenative Coupling Reactions With Redox‐Active Guanidine Reagents

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT Cross‐dehydrogenative coupling (CDC) reactions are attractive and environmentally friendly ways to form new C‐C and other element‐element bonds. Here, we report the first CDC reactions triggered by a redox‐active guanidine reagent. N‐phenyltetrahydroisoquinoline and derivatives with electron‐donating and withdrawing substituents at the N ...
Petra Walter   +2 more
wiley   +1 more source

Radiation treatment of exhaust gases. VIII. NO2 decomposition in NO2-N2 and NO2-rare gas mixtures.

open access: yesJournal of Nuclear Science and Technology, 1979
SUZUKI, Nobutake   +3 more
openaire   +1 more source

Home - About - Disclaimer - Privacy