Results 41 to 50 of about 11,127,655 (242)

Novel processing of polyhydroxybutyrate with micro- to nanofibrillated cellulose and effect of fiber morphology on crystallization behaviour of composites

open access: yeseXPRESS Polymer Letters, 2020
In this work, the intrinsic drawbacks of polyhydroxybutyrate (PHB) such as slow crystallization rate, secondary crystallization and brittle nature were improved by blending with bio-based fillers, i.e. nanofibrillated/microfibrillated cellulose (NFC/MFC).
V. K. Rastogi, P. Samyn
doaj   +1 more source

Thermodynamic Limits to Molecular Doping in Conjugated Polymers: A Perspective on Phase Behavior and Miscibility

open access: yesAdvanced Materials, EarlyView.
Molecular doping of conjugated polymers is fundamentally constrained by thermodynamic phase behavior. This Perspective reframes doping efficiency and stability in terms of miscibility limits, binodals, and solvus boundaries, highlighting the role of effective interaction parameters and charge transfer.
Somayeh Kashani   +10 more
wiley   +1 more source

Light‐Programmed Localized Supersaturation Enables Ambient Aqueous Synthesis of Highly Crystalline Metal–Organic Frameworks

open access: yesAdvanced Materials, EarlyView.
In the proposed model, a photoinduced nanoreactor uses Cu2O self‐photooxidation to generate localized supersaturation. A metastable supersaturation state first forms a shell, creating a spatially confined environment that restricts reactant exchange; continued Cu release then drives the local environment toward a labile regime that favors predominantly
Yongdeok Ahn   +5 more
wiley   +1 more source

Non-Isothermal Crystallization Behavior of Poly(vinylidene fluoride) in Dialkyl Phthalate Diluents during Thermally Induced Phase Separation Process

open access: yesCrystals, 2020
The non-isothermal crystallization behavior of poly(vinylidene fluoride) (PVDF) in dialkyl phthalate diluents during the thermally induced phase separation (TIPS) process was investigated by differential scanning calorimetry (DSC) at various cooling ...
Yakai Lin   +3 more
doaj   +1 more source

Crystallization kinetics of GdYScAlCo high-entropy bulk metallic glass

open access: yesChimica Techno Acta, 2023
The thermal stability and non-isothermal crystallization of a new bulk-amorphous high-entropy (HE-BMG) equiatomic GdYScAlCo alloy were studied by differential scanning calorimetry (DSC). The alloy shows a four-stage crystallization process.
V. A. Bykov   +3 more
doaj   +1 more source

Non-isothermal crystallization kinetics and thermal behaviour of PA12/SEBS-g-MA blends

open access: yes, 2015
International audienceThe thermal behaviour and crystallization kinetics of PA12/SEBS-g-MA blends were investigated under non-isothermal and isothermal conditions using thermogravimetric analysis and differential scanning calorimetry, respectively.
Maiti, S. N.   +3 more
core   +1 more source

Percolation‐Driven β‐Relaxation Enables Resonant Acceleration of Crystallization in Amorphous Phase‐Change Materials

open access: yesAdvanced Materials, EarlyView.
Mobile‐atom percolation underlying β‐relaxations fundamentally dictates the crystallization pathways of phase‐change materials. High‐frequency ultrasonic excitation dynamically modulates this critical mobility percolation network, substantially accelerating the crystallization process.
Yu‐Yao Liu   +11 more
wiley   +1 more source

Non-Isothermal Crystallization Kinetics of Poly(Butylene Terephthalate)/Silica Nanocomposites

open access: yes, 2009
Poly(butylene terephthalate)/silica nanocomposites were prepared by in situ polymerization of terephthalic acid, 1,4-butanediol and silica. Transmission electronmicroscopy (TEM) was used to examine the quality of the dispersion of silica in the PBT ...
Zheng K   +17 more
core   +1 more source

Crystallization Behavior and Morphology of Biodegradable Poly(ε-caprolactone)/Reduced Graphene Oxide Scaffolds

open access: yesBiomimetics, 2022
Morphology, thermal properties and the non-isothermal melt crystallization kinetics of biodegradable poly(ε-caprolactone) (PCL)/reduced graphene oxide (rGO) scaffolds are studied with differential scanning calorimetry (DSC) at various cooling rates (5 ...
Esperanza Díaz   +2 more
doaj   +1 more source

Directional Confinement Governed Ion Transport for Efficient Actuation

open access: yesAdvanced Materials, EarlyView.
Structural anisotropy provides an effective means to regulate ion transport in polymer electrolytes. Directionally aligned channels formed by freeze‐drying provide continuous pathways for ion migration, enhancing ion mobility and simultaneously improving the strain and blocking force of ionic actuators.
Yufei Zhang   +8 more
wiley   +1 more source

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