Results 201 to 210 of about 41,447 (280)

Photoreversible Polyurea Actuators With Spatiotemporal Control and Adaptive Mechanics

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A light–thermal responsive polyurea network incorporating reversibly dimerizable anthracene units enables spatiotemporal modulation of cross‐linking density and nearly 400‐fold stiffness tuning. Integrating programmable anisotropy, photopatterning, self‐healing, and photowelding within a single framework, this bioinspired “one network–multifunction ...
Zhiwen Song, Wang Li, Xinru Guo, Rui Pu, Wenxin Wang, Yujun Cheng, Liang Shen, Fei Gao   +7 more
wiley   +1 more source

In Situ Phase Transition and Cu Doping Synergistically Regulate Perovskite Z‐Scheme Heterojunction for Photocatalytic CO2 Reduction

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A novel in situ synthesis strategy is proposed for fabricating Cu‐CsPbBr3/Cu‐CsPb2Br5 heterojunction materials, with dual optimization of structure and composition expanding the CO2 adsorption/activation area and enhancing intrinsic catalytic activity.
Qiliang Zhu, Jia Sun, Yihua Zhu, Haibo Jiang, Wei Yan, Jianhua Shen   +5 more
wiley   +1 more source

On the Planarity of Heterocyclic Bay‐Substituted Perylenediimides: Insight into the Fluorescent Photoinduced Electron Transfer Sensing Framework

European Journal of Organic Chemistry, EarlyView.
Near‐infrared fluorescent pH indicators based on perylenediimide were constructed in a modular receptor–spacer–fluorophore–spacer–receptor format with heterocyclic amino moieties at the bay positions. Counterintuitively, the dibrominated intermediate with two heavy atoms is more emissive than the heterocyclic compounds.
Luke Camenzuli, Davide Benedetto Tiz, Nicola’ Agius, Konrad Szaciłowski, David C. Magri   +4 more
wiley   +1 more source

Non-photochemical quenching may contribute to the dominance of the pale mat-forming lichen Cladonia stellaris over the sympatric melanic Cetraria islandica. [PDF]

Oecologia
Solhaug KA, Eiterjord G, Løken MH, Gauslaa Y.   +3 more
europepmc   +1 more source

Stereoselective Synthesis of Glycomimetic Amines From Biomass‐Derived Cyrene

European Journal of Organic Chemistry, EarlyView.
2,3,4‐Trideoxy‐2‐mannosamines, including the unsubstituted one, are accessible as the only endo diastereoisomers by reductive amination of the green solvent Cyrene, derived from pyrolysis of cellulose containing waste biomass. The products are useful chiral synthetic intermediate to nitrogenated glycomimetics.
Debora Pratesi, Marta Rigacci, Francesca Cardona, Camilla Matassini, Andrea Goti   +4 more
wiley   +1 more source

Emerging Trends in Organic Photoreactions Utilizing Disulfides

European Journal of Organic Chemistry, EarlyView.
Disulfides are versatile, nontoxic alternatives to metal photocatalysts. This review explores their role as photoactivated thiyl‐radical precursors and bifunctional catalysts (HAT/electron shuttling) in diverse transformations. Strategies for electronic tuning and development into recyclable heterogeneous materials are highlighted for sustainable ...
Sunil Kumar, Bolormaa Bayarkhuu, Hong Y. Cho, Jeehye Byun   +3 more
wiley   +1 more source

Preparation of α‐Mono‐Fluoromethyl Silanes via Nucleophilic Displacement on Chlorosilanes With LiCH2F

European Journal of Organic Chemistry, EarlyView.
The SiCl bond acts as a versatile platform for undergoing a formal nucleophilic substitution promoted by LiCH2F en route to extremely rare α‐monofluoromethyl‐silanes. Though surprising – when compared with well‐established poly‐fluoromethyl silanes (e.g., Ruppert‐Prakash reagent, TMSCF3) – α‐mono‐fluoromethyl silanes are underrepresented motifs in ...
Alberto Nardi, Davide Castiglione, Margherita Miele, Laura Castoldi, Vittorio Pace   +4 more
wiley   +1 more source

Retraction Note: Increased biomass productivity in green algae by tuning non-photochemical quenching. [PDF]

Sci Rep, 2019
Berteotti S, Ballottari M, Bassi R.
europepmc   +1 more source

Hofmann Degradation of Asparagine and Glutamine as an Efficient Approach for the Synthesis of Derivatized Lysine Homologs

European Journal of Organic Chemistry, EarlyView.
A practical and scalable route to C1 and C2 lysine homologs has been developed using Hofmann degradation of N‐protected L‐asparagine and L‐glutamine as the key step. These short‐tether scaffolds enable efficient synthesis of diverse Fmoc‐protected noncanonical amino acids (ncAAs) bearing donor, acceptor, redox‐active, and fluorescent residues.
Adelaide R. Mashweu, François J. De Beer, Jolien Bertouille, Steven Ballet, Charlotte Martin, Ulrich Hennecke, Charlene Marais, Vladimir A. Azov   +7 more
wiley   +1 more source

In vitro and in vivo investigation of chlorophyll binding sites involved in non-photochemical quenching in Chlamydomonas reinhardtii. [PDF]

Plant Cell Environ, 2019
Perozeni F, Cazzaniga S, Ballottari M.
europepmc   +1 more source