Results 111 to 120 of about 2,252,922 (304)

Catalyst‐Free Selective Reduction of Nitrogen Dioxide to Nitric Oxide

open access: yesChemistry – A European Journal, EarlyView.
Common main group reductants selectively convert nitrogen dioxide to nitric oxide in a catalyst‐free manner. Computational studies suggest divergent reaction pathways depending on the reductant employed. Where boranes and silanes proceed via a two‐electron process, and hydrogen surrogates undergo stepwise one‐electron processes.
Awais W. Seyyad   +3 more
wiley   +1 more source

VOCs Adsorption and Exchange Properties in Bispidine‐Based Mn(II) 1D CPs Made of Orthogonally Oriented Linear Chains

open access: yesChemistry – A European Journal, EarlyView.
Combining the chiral bispidine ligand L1 with MnCl2 affords coordination polymers (CPs) with an unusual topology for this family of compounds, consisting of orthogonally packed ribbon‐like one‐dimensional (1D) chains. Their behavior was investigated through single‐crystal‐to‐single‐crystal exchange with aromatic volatile organic compounds (VOCs) and ...
Meriem Goudjil   +8 more
wiley   +1 more source

Impacts of Interannual Isoprene Variations on Methane Lifetimes and Trends

open access: yesGeophysical Research Letters
Recent observations show anomalously high methane growth in 2020, which has been attributed to increased wetland emissions and decreased OH from lower COVID‐19 nitrogen oxide (NOx) emissions. NOx is not the only species that affects OH—isoprene, the most
James (Young Suk) Yoon   +5 more
doaj   +1 more source

NOx formation processes in rotating detonation engines

open access: yesFrontiers in Aerospace Engineering
High-fidelity simulations of RDEs with H2-Air-NOx chemistry are employed to study NOx emissions in such devices. Discrete injection of gaseous hydrogen fuel and continuous injection of air oxidizer is used at various mass flow rate conditions in several ...
Caleb Van Beck, Venkat Raman
doaj   +1 more source

The Rich Chemistry of Ionized Methanol With Sulfur Dioxide: Pathways to Prebiotic and Elusive Species in Earth's Atmosphere and Space

open access: yesChemistry – A European Journal, EarlyView.
The reaction between the methanol radical cation and sulfur dioxide is remarkably fast and forms several ionic and neutral products (HOSOH+, CH2OSO+, CH2OH+, CH2O, H2O, HSO2). The chemistry goes beyond simple proton or hydrogen transfer, revealing a close interaction between the two species, relevant to atmospheric and astrochemical environments where ...
Mauro Satta   +3 more
wiley   +1 more source

Numerical simulation of premixed methanol combustion characteristics in a swirl burner

open access: yesCase Studies in Thermal Engineering
Burner pollutant emissions are a significant source of atmospheric nitrogen oxides (NOx), posing an ongoing challenge for low-NOx design. This study uses Fluent software to numerically simulate a methanol sleeve-type swirl burner, employing the eddy ...
Jingfei Li   +3 more
doaj   +1 more source

Bismuth Chalcogenide‐Based Photocatalysts for Nitrogen Reduction: Recent Progress and Prospects

open access: yesChemistry – A European Journal, EarlyView.
Bismuth chalcogenides emerge as promising visible‐light photocatalysts for sustainable ammonia synthesis, driven by tunable electronic structures and strong N2 activation. Recent advances reveal how defects, doping and heterojunction design synergistically enhance charge separation and reactivity. Key challenges and future directions highlight pathways
Mukesh K. Verma   +4 more
wiley   +1 more source

Air Quality Implications of Using Ammonia as a Renewable Fuel: How Low Can NOx Emissions Go? [PDF]

open access: yesACS Energy Lett, 2023
Gubbi S   +6 more
europepmc   +1 more source

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