Results 101 to 110 of about 97,090 (245)

Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth‐Ligand Cooperation

Chemistry – A European Journal, EarlyView.
ABSTRACT Over the past twenty years, main group chemistry has significantly expanded its scope to include reactivities once considered the exclusive domain of transition metals. Among the emerging concepts, element‐ligand cooperation has proven to be a powerful strategy for enabling bond activation reactions but remains relatively unexplored for ...
Lennart Hensle, Viktoria H. Gessner
wiley   +1 more source

Distinct Ligand‐ and Metal‐Centered Phosphorescence in a Terbium Carbazolyl Complex

Chemistry – A European Journal, EarlyView.
Terbium and lanthanum carbazolide complexes show two distinct modes of luminescence: Strongly temperature‐dependent narrow‐line terbium emission could be induced. In addition, both the terbium and the lanthanum complexes show broad‐line interligand emission processes with excited states of microsecond life‐time.
Xiaofei Sun, Frederic Krätschmer, Julia Feye, Marcel Lukanowski, Dominik Graf, Sergei Lebedkin, Manfred Kappes, Florian Weigend, Peter W. Roesky, Alexander Hinz   +9 more
wiley   +1 more source

Substituent‐Controlled Ring Opening of 1‐Substituted Benzocyclobutenes: Electronic Structure and Diradical Character of Ortho‐Quinodimethane Intermediates

Chemistry – A European Journal, EarlyView.
Experimental and computational studies elucidate how the electronic nature of substituents controls the ring‐opening temperature and diradical character of 1‐substituted benzocyclobutenes, enabling the rational design of o‐quinodimethane‐based synthetic transformations.
Magali Dallegre, Imen Abid, Roselyne Rosas, Maxime Dousset, Gaëlle Chouraqui, Laurent Commeiras, Didier Siri, Didier Gigmes, Anthony Kermagoret   +8 more
wiley   +1 more source

Variable Temperature Studies of Two Calcium Uranates α‐Ca3UO6 and Ca2UO5

Chemistry – A European Journal, EarlyView.
The structures and thermal responses of the calcium uranates α‐Ca3UO6 and Ca2UO5 were investigated using in situ synchrotron x‐ray diffraction and neutron powder diffraction. Despite the very similar chemical compositions, the structural response of the two calcium uranates is shown to be complex and varied.
Maria K. Nicholas, Timothy A. Ablott, Caleb J. Bennett, Bryce G. Mullens, Helen E. Maynard‐Casely, Wen Liang Tan, Jeremy L. Wykes, Yingjie Zhang, Brendan J. Kennedy   +8 more
wiley   +1 more source

A High Energy Barrier DyIII2 Single‐Molecule Magnet Supported by a Bulky, Anionic N–O Bridging Ligand

Chemistry – A European Journal, EarlyView.
Complex [Dy2(hynad)2(dbm)4] was prepared by the employment of the anionic N–O‐based bridging and chelating N‐hydroxy‐1,8‐naphthalimide ligand, featuring a {Dy2(µ‐OR)2}4+ core and exhibiting zero‐field SMM behavior with a Ueff value of 171 K and double‐S‐shaped hysteresis loops, open up to 3.5 K.
Alexandros S. Armenis, Concepción Molina‐Jirón, Konstantinos N. Pantelis, Wolfgang Wernsdorfer, Mario Ruben, Eufemio Moreno‐Pineda, Theocharis C. Stamatatos   +6 more
wiley   +1 more source

Dinuclear Copper(I) Complexes Featuring Metal–Metal Interactions and a μ2‐Bridging Phosphane With Additional Olefinic Binding Sites

Chemistry – A European Journal, EarlyView.
A Cu2P triangle captured in a tetrapodal phosphane tris(olefin) ligand, where all binding forces are weak apart from the Cu─P interaction. ABSTRACT The molecule Ptrop3 contains in each trop unit (trop = dibenzo[a,d]cyclohepten‐5‐yl) a rigid central seven‐membered ring with an olefinic binding site making Ptrop3 potentially a tetradentate ligand ...
Zhongshu Li, Daniel Himmelbauer, Jan Oswald, Michael Wörle, René Verel, Zoltán Benkő, Hansjörg Grützmacher   +6 more
wiley   +1 more source

Exploring Tradeoffs in Syngas Production With Solid‐Oxide Electrolysis via Multi‐Objective Optimization

Chemie Ingenieur Technik, EarlyView.
This work applies multi‐objective optimization to investigate trade‐offs between different objectives in syngas production with solid‐oxide cell co‐electrolysis. Two system designs are investigated. By systematically exploring tradeoffs between different objectives, insights, and comparisons of the operation of these designs are achieved.
Gbenga Jerome, Victor Selmert, An Phuc Dam, Nicolas Kruse, Leandros Paschalidis, Remzi Can Samsun, Rüdiger‐A. Eichel   +6 more
wiley   +1 more source

In‐situ asphaltene capture with iron oxide nanoparticles in steam‐assisted gravity drainage (SAGD) for improved recovery and partial upgrading of bitumen

The Canadian Journal of Chemical Engineering, EarlyView.
Key improvements obtained by incorporating nanoparticles into a lab‐scale SAGD process configuration. The bar plots show enhanced oil recovery, reduced viscosity, and increased asphaltene adsorption in nanoparticle‐assisted scenarios compared with conventional SAGD.
Luis Prada, Saleh S. Baakeem, Mabkhot BinDahbag, M. Daniela Contreras‐Mateus, Jesus Botett, Afif Hethnawi, Nashaat N. Nassar   +6 more
wiley   +1 more source

Engineering the Lattice and Electronic Configurations of N‐Rich‐CoMoCN by Mo Doping and N Enrichment for Enhanced Water Splitting

EcoEnergy, EarlyView.
This study design Mo‐doped and N‐rich‐CoMoCN bimetal for bi‐functionally efficient overall water splitting catalysts by constructing an active site and engineering the interfacial Co6Mo6C2/Co heterojunction in a N‐doped porous carbon matrix and study on the performance of catalyst for electrocatalytic.
Huimin Yang, Yue Xiao, Zhuo Wang, Mingfang Zhang, Haimei Xu, Yunzhao Fan, Chao Feng, Qingcheng Hu, Chunhua Yuan, Yang Fu, Lingfeng Zhu, Songbo Li, Tianyi Ma   +12 more
wiley   +1 more source

Bis(μ-3,5-dinitrobenzoato-κ2O1:O1′)bis(μ-3,5-dinitrobenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3,5-dinitrobenzoato-κ2O1,O1′)(1,10-phenanthroline-κ2N,N)dysprosium(III)]

Acta Crystallographica Section E, 2011
In the binuclear title complex, [Dy2(C7H3N2O6)6(C12H8N2)2], the DyIII ions exhibit a distorted monocapped square-antiprismatic geometry and are coordinated by seven O atoms of four 3,5-dinitrobenzoate (DNBA) anions and two N atoms of a phenanthroline ligand. The carboxylate groups of the DNBA anions exhibit three coordination modes: bidentate chelating,
Gai-Qing Xi, Ning Ren, Da-Hai Zhang, Chun-Hua Dong, Juan-Juan Hao   +4 more
openaire   +1 more source