Synthesis and Optical Properties of Diboron Complexes of 1,4‐Anthraquinone Derivatives
1,4‐Diboron complexes exhibit near‐infrared fluorescence, in contrast to non‐emissive 1,5‐diboron analogues. Fluorescence quantum yields decrease with increasing electron‐donating substituents, attributed to enhanced nonradiative decay via intramolecular PeT.
Yasuhiro Kubota +10 more
wiley +1 more source
Pyridylalkenolato-Stabilized Heavier Tetrylenes: Air-Stability Studies and Preliminary Coordination Chemistry. [PDF]
García-Vega S +3 more
europepmc +1 more source
A sustainable route to photoresponsive molecular systems is achieved using the bio‐based flavanone (‐)‐isolonchocarpin from Tephrosia vogelii. Through McMurry homocoupling and light‐driven 6‐π‐electrocyclization, an overcrowded alkene and a fluorescent O‐heterocyclic phenanthrene are synthesized.
Deryl H. Limawan +8 more
wiley +1 more source
Synthesis and crystal structure of <i>catena</i>-poly[[[aqua-(2,3-di-methyl-pyrazine-κ<i>N</i>)cadmium(II)]-di-μ-bromido] 2,3-di-methyl-pyrazine monosolvate hemihydrate]. [PDF]
Näther C.
europepmc +1 more source
Oxidative Generation and Reactivity of the Cyclopropyl Radical From a Martin Silicate
A photoredox strategy employing Martin silicates enables the oxidative generation and controlled capture of cyclopropyl radicals, including the naked one, long considered challenging intermediates. The method affords functionalized cyclopropanes through both Giese‐type additions and dual nickel/photoredox C(sp3)−C(sp2) cross‐couplings.
Amal Lakhal +3 more
wiley +1 more source
Odor-induced sweetness enhancement: EEG evidence for olfactory and gustatory cross-modal interactions. [PDF]
Yang Y +5 more
europepmc +1 more source
Azidophosphonamido Rhodium(I) and Iridium(I) Complexes: Synthesis, Properties, and Linkage Isomerism
A family of azidophosphonamido ligands and their corresponding rhodium(I) and iridium(I) complexes were synthesized. The rich reaction chemistry of these species revealed unusual linkage isomerization processes and bonding motifs. M = Rh, Ir; Mes = 2,4,6‐Me3C6H2. ABSTRACT A series of azidophosphonamido rhodium(I) and iridium(I) complexes ([iPr2P(N3R)NR]
Emily L. Trew +3 more
wiley +1 more source
Cell-o1 : training LLMs to solve single-cell reasoning puzzles with reinforcement learning. [PDF]
Fang Y +9 more
europepmc +1 more source
Survey of in vitro susceptibilities of Vibrio cholerae O1 and O139 to antimicrobial agents
Vibrio cholerae O139 (173 strains) and O1 (221 strains) were tested for their in vitro susceptibilities to 39 antimicrobial agents. Both O139 and O1 strains were highly susceptible to azithromycin, cephems, minocycline, penems, and newer fluoroquinolones.
Nair, G. B. +4 more
core
Germylium Catalyzed Dehydrofluorination Reactions of Fluorinated Alkanes
Dehydrofluorination reactions of fluorinated alkanes catalyzed by germylium ions are reported. Computational studies of the mechanism revealed an E2 type mechanism involving a germane as a base to facilitate olefin formation in competition with an SN2 mechanism for hydrodefluorination.
Julie Borel +3 more
wiley +1 more source

