Experimental Observation of a Calcium Silicon Double Carbonate
High‐pressure and ‐temperature reactions between Ca5(Si2O7)(CO3)2 tilleyite and CO2 carbon dioxide yield the first experimental evidence of the double carbonate Ca2Si(CO3)4 and a new Ca2(C4O10) phase containing tetrahedral [CO4] units. These findings reveal unexpected carbonate chemistry and highlight pathways for carbon incorporation under mantle ...
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