Results 151 to 160 of about 1,424,500 (295)

High‐Energy‐Density Redox Flow Batteries: Mechanisms, Design Strategies, and Recent Progress

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT The inherent intermittency of energy sources such as solar and wind power hinders the transition to renewable energy, necessitating advanced energy storage solutions. Enhancing energy density is crucial for lowering system costs and enabling large‐scale deployment.
Xiaolian Zhao   +8 more
wiley   +1 more source

Toward Larger Cyclo‐9,10‐Anthryleneparaphenylenes

open access: yesChemistry – A European Journal, EarlyView.
During a macrocyclization with a dihydroanthracene diol as corner unit, larger oligomers than the trimer and tetramer were formed and isolated up to the nonamer. Their three‐dimensional structures were studied by X‐ray diffraction. The most abundant macrocycles were rearomatized to the corresponding CPP derivatives.
Moritz P. Schuldt   +3 more
wiley   +1 more source

Benzo[cd]azulenyl: A Structural Isomer of Phenalenyl—Synthesis and Properties of Its Tri‐tert‐butyl‐substituted Derivative and Formation of a Thermal‐ and Photoresponsive σ‐Dimer

open access: yesChemistry – A European Journal, EarlyView.
Benzo[cd]azulenyl, a nonalternant isomer of phenalenyl, is identified as a new member of the nonalternant hydrocarbon radical family. The tri‐tert‐butyl substituted derivative forms a stable σ‐dimer in the solid state. Upon exposure to external stimuli such as light and heat, the σ‐bond of the dimer dissociates, producing the monomeric radical.
Kaho Takeuchi   +2 more
wiley   +1 more source

A Novel Heterometallic Ring {Cr5Ni3} and New {Cr6Co2} and {Cr6Zn2} Rings

open access: yesChemistry – A European Journal, EarlyView.
A novel heterometallic ring containing five Cr(III) and three Ni(II) centers is reported. It forms an octagon and has a single isomer, as revealed by a combination of magnetic and EPR studies and collision‐induced dissociation mass spectrometry. ABSTRACT A new heterometallic ring, [Me4N][(Me4N)2Cr5Ni3F8(BTFB)16] (BTFB = 3,5‐bis(trifluoromethyl)benzoate)
Abdulelah Alsuhaymi   +9 more
wiley   +1 more source

Homo‐/Heterodimeric Substrates Bias the Type and Multiplicity of Hydroxamic Acid Chelators Assembled by a NIS Synthetase DesD

open access: yesChemistry – A European Journal, EarlyView.
Chemoenzymatic reactions using the siderophore synthetase DesD from Salinispora tropica and hydroxamic acid substrates (native, non‐native) with different multiplicities (monomer, dimer) and components (homo‐/heterodimer) followed different reaction trajectories, which biased the architectures of the chelator major products and indicated DesD contains ...
Callum A. Rosser   +2 more
wiley   +1 more source

Quasideuteron Mode in Odd-Odd N=Z Nuclei [PDF]

open access: yes, 2002
Lisetskiy, Alexander
core  

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