Results 131 to 140 of about 44,933 (293)

Insights Into Symmetry and Substitution Patterns Governing Singlet–Triplet Energy Gap in the Chemical Space of Azaphenalenes

Chemistry – A European Journal, EarlyView.
ABSTRACT Molecules that violate Hund's rule by exhibiting an inverted singlet–triplet gap (STG), where the first excited singlet (S1${\rm S}_1$) lies below the triplet (T1${\rm T}_1$), are rare but hold great promise as efficient fifth‐generation light emitters.
Atreyee Majumdar, Raghunathan Ramakrishnan   +1 more
wiley   +1 more source

Emissive Liquid Crystalline Boron C,N‐Chelates: Synthesis, Self‐assembly, and Photophysical Properties

Chemistry – A European Journal, EarlyView.
Novel emissive liquid crystalline boron C,N‐chelates were prepared by integrating mesogenic units into the boron C,N‐core. Depending on the substituent at the boron, stable SmA or N mesophases were achieved while maintaining intense blue emission with excellent quantum yields (61%–100%).
Franziska Müller, Falk Feucht, Alexander Beck, Ramona Seher, Anna Zens, Johannes Kästner, Yann Molard, Sabine Laschat   +7 more
wiley   +1 more source

Synthesis and Characterization of Carbazole‐Containing Aza[7]helicenes

Chemistry – A European Journal, EarlyView.
Double ortho fusion led to different aza[7]helicene frameworks showing strong acidochromic behavior, singlet excited energies being more than twice the triplet energy, and high racemization barriers, allowing chiral resolution and ECD measurements. ABSTRACT Azahelicenes have attracted significant interest due to their intrinsic axial chirality and ...
Inka Marten, Melina E. A. Dilanas, Joachim Podlech   +2 more
wiley   +1 more source

Accessing Sn≥2 States of a TADF Emitter by Femtosecond NIR Spectroscopy

Chemistry – A European Journal, EarlyView.
The depicted thermally activated delayed fluorescence (TADF) emitter was studied by femtosecond near‐infrared (NIR) spectroscopy. A prominent NIR transition was shown to be strongly solvent‐dependent, with implication for intersystem crossing in the compound.
Wiebke Haselbach, Jasmin Matthes, Andreas Prüfer, Simon L. Zimmermann, Monika Flörke, Thomas J. J. Müller, Peter Gilch, Barbara E. Nogueira de Faria   +7 more
wiley   +1 more source

Molten Zinc Coordination Polymer Glass as a Host for Stable and Processable Optical Dye Composites

EcoEnergy, EarlyView.
Zinc‐based coordination polymer glass is employed to suppress aggregation‐caused quenching (ACQ) and enhance molecular stability, enabling improved luminescence performance in the solid state. The emission color of the hybrid composites can be tuned by varying the incorporated guest molecules, while the glass matrix effectively prevents aggregation and
Jaeho Lee, Wengang Huang, Yoshiki Sugai, Xiangyi Zha, Yuelei Chen, Joshua A. Powell, Yi‐Chen Hsu, Zixi Xie, Vicki Chen, Lianzhou Wang, Jingwei Hou   +10 more
wiley   +1 more source

No Charging but Protection: Lifetime Prolongation of Spontaneously‐polarized Electrets for Energy Harvesting Applications

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A bilayer protection approach is proposed for slowing down the surface potential decay of thin films of spontaneously‐polarized electret materials. The electret and the protective films are characterized, and the protection effectiveness is investigated under the effects of light illumination, water contact and mechanical impact.
Seyedali Sabzpoushan, Henry Juncker, Peter Woias   +2 more
wiley   +1 more source

Phosphorescent Platinum(II) Complexes With Diazinedipyrrolide Pincer Ligands: Structure and Photophysical Properties

European Journal of Inorganic Chemistry, EarlyView.
A new family of phosphorescent Pt(II) complexes with pyrimidinedipyrrolide ligands, including a pyrazine analog, was designed and synthesized. Their emission properties can be finely tuned via ligand modification, revealing strong phosphorescence originating from intraligand charge transfer transitions.
Marcela Horáková, Alexandre Rico, Filip Bureš, Pascal le Poul, Sébastien Gauthier, Jiří Váňa, Zdeňka Růžičková, Sylvain Achelle   +7 more
wiley   +1 more source

Flexible Multi‐Mode Electrochromic Displays for Human Motion Monitoring and Pattern Display in Dark Environments

Exploration, EarlyView.
The reflective nature of electrochromic displays limits their display functionality and human motion monitoring in dark environments. This work presents a flexible multi‐mode electrochromic display (FMECD) with high optical modulation (75.8%) and low energy consumption (0.004% of OLEDs). Integrating EC, PL, and ML functions, it enables continuous, real‐
Xue Chen, Qi Zhao, Li Wang, Xin Yu, Xu Liang, Zhang Chen, John Wang, Yanfeng Gao   +7 more
wiley   +1 more source

Blue‐hazard‐free single‐emissive‐layer white organic LEDs based on an anti‐quenching narrowband blue emitter

FlexMat, EarlyView.
A blue‐hazard‐free single‐emissive‐layer white OLED is realized using an anti‐quenching multiple‐resonance TADF emitter, BNCT. By integrating a sterically protected MR core with efficient energy transfer capability, BNCT enables warm‐white emission with high efficiency, negligible hazardous blue photons, and a simplified device architecture for next ...
Xiao‐Long Liu, Wei‐Le Wu, Ru‐Jia Wang, Xin‐Lu Li, Jia‐Ming Jin, Ji‐Hua Tan, Hong‐Ji Tan, Yanping Huo, Hao‐Li Zhang, Wen‐Cheng Chen   +9 more
wiley   +1 more source

Thermally activated delayed fluorescence exciplex sensitizers with fast reverse intersystem crossing for improving efficiency stability of organic light‐emitting diodes based on multi‐resonance emitters

FlexMat, EarlyView.
Two exciplex emitters are constructed based on a host‐guest doping strategy, and their exciton dynamics processes are investigated in depth. High‐performance OLEDs are fabricated by employing these exciplexes as emitters or sensitizers, providing excellent electroluminescence efficiencies and low efficiency roll‐offs.
Jingwen Xu, Min Wang, Jinshi Li, Ben Zhong Tang, Zujin Zhao   +4 more
wiley   +1 more source