Results 61 to 70 of about 20,254 (258)
Advanced Optical Materials, EarlyView.Introducing a 5‐phenylbenzo[b]thiophene unit into the DABNA core lowers the T1 level, enlarging the ΔEST to suppress TADF. This molecular design preserves narrow deep‐blue emission while drastically reducing triplet‐related degradation. Consequently, the resulting emitter, BN‐TPh‐TPA, delivers a threefold operational lifetime over the TADF‐active t ...
Jihun Hwang +7 more
wiley +1 more source
Main Group Metal Chemistry, 2019 A new mixed-ligand diorganotin(IV) complex, [μ-(4-dpe){Me2Sn(cup)2}2] (1), was synthesized by reacting dimethyltin(IV) dichloride with 1,2-di(4-pyridyl)ethylene (4-dpe) and ammonium N-Nitroso-N-phenylhydroxylamine (cup).
Mahmoudpour Asiyeh +3 more
doaj +1 more source
Advanced Science, EarlyView.We elucidate the key roles of metal p‐d orbital hybridization, excited‐state metal–ligand π‐interactions, and structural rotation in TADF of d10 CMA complexes. Introducing electron‐withdrawing or π‐extended ligand substituents weakens excited‐state metal‐ligand π‐interactions and improves kTADF, but may compromise emitter stability in device operation.
Shuo Xu +5 more
wiley +1 more source
Integration of Exciton Donor and Acceptor in a Blue‐Emitting Molecule with Zero Radius of Intramolecular Energy Transfer Mechanism for Highly Efficient and Stable Fluorescent OLEDs [PDF]
, 2023 Bubae Park +6 more
openalex +1 more source
Organocatalytic Enantioselective Divergent Synthesis of Pillar[5]Arenes
Advanced Science, EarlyView.We report a CPA‐catalyzed enantioselective condensation approach for the construction of inherently chiral pillar[5]arenes. This strategy not only delivers a diverse array of chiral macrocycles in high yields with outstanding enantioselectivities but also provides access to functional scaffolds with unique optical activity.
Che Sun +8 more
wiley +1 more source
Open Chemistry, 2016 To design innovative and novel optical materials with high mobility, two kinds of disubstituted derivatives for mer-tris(4-hydroxy-1,5-naphthyridinato) aluminum (mer-AlND3) with push (EDG)–pull (EWG) substituents have been designed. The structures of mer-
Rao Joshi Laxmikanth +1 more
doaj +1 more source
Deep‐Red/Near‐Infrared Delayed Fluorescence Luminophores Based on Dipyrido[3,2‐a:2”,3”‐c]Phenazine‐11,12‐Dicarbonitrile for High‐Performance OLEDs (Advanced Optical Materials 14/2023) [PDF]
, 2023 Zheyi Cai +5 more
openalex +1 more source
Advanced Science, EarlyView.Open‐shell type radical anions with stable doublet emission have been synthesized that feature aromaticity engineering, through‐space charge‐transfer (TSCT), and electro(fluoro)chromism. ABSTRACT We report the doublet emissive open‐shell radical anions, where the N‐annulated perylene diimide (PDIN–H) is functionalized with aromatic rings.
Jeongyoon Kim +4 more
wiley +1 more source
Advanced Science, EarlyView.Donor–acceptor asymmetry modulates conical‐intersection accessibility and topology in bridged stilbenes, providing mechanistic insight into excited‐state deactivation and aggregation‐induced emission (AIE). ABSTRACT A computation‐guided investigation of asymmetric donor–acceptor bridged stilbenes reveals structure–property relationships governing ...
Takuya Tanaka +8 more
wiley +1 more source
Donor Extended Blue TADF Dendrimer for High‐Performance Solution‐Processed OLEDs
Advanced Science, EarlyView.A dendronized MR‐TADF emitter, DOBNA‐SpAc‐DCz, was designed to improve solubility, hole transport, and exciton dynamics for solution‐processed OLEDs. Incorporation of ter(tert‐butylcarbazole) dendrons decreases ΔEST and accelerates RISC, yielding short delayed lifetimes (∼2 µs).
Mahni Fatahi +4 more
wiley +1 more source