Results 91 to 100 of about 17,166 (245)

Dichloropalladium complexes ligated by 4,5-bis(arylimino)pyrenylidenes: Synthesis, characterization, and catalytic behavior towards Heck-reaction [PDF]

, 2013
A series of 4,5-bis(arylimino)pyrenylidenylpalladium(II) chloride complexes (C1–C4) were synthesized and characterized by FT-IR and NMR spectroscopy, elemental analysis as well as by single crystal X-ray diffraction for the representative complexes C1 ...
Kong, Shaoliang, Liu, Qingbin, Redshaw, Carl, Song, Kuifeng, Sun, Wen-Hua   +4 more
core   +1 more source

Operando X‐ray Spectroscopy Study of Pd and Pd–Au Laterally Condensed Catalysts during Selective Acetylene Hydrogenation: The Role of Carbon

Advanced Materials, EarlyView.
The selective hydrogenation of acetylene over laterally condensed Pd and Pd–Au catalysts (LCCs) was investigated using operando X‐ray absorption and photoelectron spectroscopy in combination with density functional theory. Pd‐LCCs were found to incorporate significantly more carbon into the metal lattice than Pd–Au LCCs, where the carbon uptake governs
Eylül Öztuna, Thomas Götsch, Daniel Cruz, Patrick Zeller, Olga V. Vinogradova, Zehua Li, Christian Rohner, Franz‐Philipp Schmidt, Zahra Gheisari, Alexander Steigert, Martin Muske, Michael Hävecker, Eugen Stotz, Iryna Antonyshyn, Frank Girgsdies, Olaf Timpe, Thomas Lunkenbein, Vanessa J. Bukas, Karsten Reuter, Robert Schlögl, Katarzyna Skorupska, Axel Knop‐Gericke, Beatriz Roldán Cuenya   +22 more
wiley   +1 more source

Cis-Selective Ring-Opening Metathesis Polymerization with Ruthenium Catalysts [PDF]

, 2012
Cis-selective ring-opening metathesis polymerization of several monocyclic alkenes as well as norbornene and oxanorbornene-type monomers using a C–H activated, ruthenium-based metathesis catalyst is reported.
Fedorov, Alexey, Grubbs, Robert H., Keitz, Benjamin K.   +2 more
core   +2 more sources

Rewriting Polymer Fate via Chemomechanical Coupling

Advanced Materials, EarlyView.
This work introduces a life‐like “living” polymer platform that can grow, degrow, and reprogram its properties after fabrication. By integrating mass transport, reversible polymerization, and controlled catalysis, the material achieves on‐demand changes in size, shape, and mechanical properties.
Jiahe Huang, Haohui Zhang, Jiehao Chen, Xuelin Sui, Febby Krisnadi, Dongjing He, Huajian Ji, Will R. Gutekunst, Michael D. Dickey, Yuhang Hu   +9 more
wiley   +1 more source

Observation of Different Catalytic Activity of Various 1-Olefins during Ethylene/1-Olefin Copolymerization with Homogeneous Metallocene Catalysts

Molecules, 2011
This research aimed to investigate the copolymerization of ethylene and various 1-olefins. The comonomer lengths were varied from 1-hexene (1-C6) up to 1-octadecene (1-C18) in order to study the effect of comonomer chain length on the activity and ...
Mingkwan Wannaborworn, Bunjerd Jongsomjit, Piyasan Praserthdam   +2 more
doaj   +1 more source

Engineering Free Volume within Frontal Ring‐Opening Metathesis Polymerization via Pendant Plasticization

Advanced Materials, EarlyView.
Norbornene‐based copolymers with tunable n‐alkyl pendant length provide control over matrix free volume, enabling elastomeric materials via frontal ring‐opening metathesis polymerization (FROMP). ABSTRACT Frontal ring‐opening metathesis polymerization (FROMP) enables rapid, energy‐efficient access to high‐performance thermosets and thermoplastics, but ...
Kevin A. Stewart, Francesca J. Lombardi, Sky D. Cao, Claire M. Massouh, Jacob J. Lessard   +4 more
wiley   +1 more source

Microwave‐Assisted Aqueous Synthesis of Gelatin‐Norbornene for Hydrogel Crosslinking and Bioprinting

Advanced Materials Technologies, EarlyView.
A microwave‐assisted reaction is utilized to synthesize gelatin‐norbornene (GelNB), achieving a high degree of norbornene functionalization while reducing the macromer's upper critical solution temperature. The resulting GelNB macromer has high solubility at room temperature, facilitating light‐based 3‐dimensional (3D) printing of thiol‐norbornene ...
Jonathan B. Bryan, Chien‐Chi Lin
wiley   +1 more source

An infrared investigation of the catalyst formation in the system Ni(acac)2, C3H4, (iBu)3AL for propadiene polymerization [PDF]

, 1977
The catalyst formation in the system Ni(acac)2, C3H4, (iBu)3Al was investigated by means of infrared spectroscopy. It was found that the Al(acac)3 and (iBu)2Al(acac) formed are both by-products of catalyst formation without a catalytic activity.
Berkel, P.C.J.M. van, Mars, P., Ommen, J.G. van, Ploeg, H.J. van der   +3 more
core   +3 more sources

A Review on Microreactor Design for Effective Fischer–Tropsch Process Intensification

Advanced Materials Technologies, EarlyView.
Design strategies for effective Fischer–Tropsch process intensification are summarized based on experimental and simulation experiences. Recommendations for catalyst loading of packed‐bed and wash‐coated microchannel, microtube, micromonolith, and microstructured reactors are discussed.
Yangjun Wei, Lukas Thum, Avela Kunene, Daniel Amkreutz, Rutger Schlatmann, Sonya Calnan   +5 more
wiley   +1 more source

"Research progress in polymerization of conjugated dienes catalyzed by neodymium based catalysts （Part Ⅱ）"

Hecheng xiangjiao gongye
With the widespread application of conjugated dienes, there were higher requirements for the performance of poly(conjugated dienes) rubber. By adjusting polymerization pathway, specific polymer chain structures could be obtained to meet diverse ...
YOU Jing-yu, GONG Di-rong
doaj   +1 more source