Results 171 to 180 of about 26,493 (337)
European Journal of Inorganic Chemistry, EarlyView.The first low‐oxidation (I/III) state chromium‐complex bearing a O‐chelating NHC ligand has been synthesized and structurally characterized by single‐crystal X‐ray analysis. The formation of the mixed‐valence species was further supported by SQUID magnetometry and high‐field electron paramagnetic resonance (EPR) spectroscopy.
Somnath Bhattacharya +4 more
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Structure and dynamics of catalytically competent but labile paramagnetic metal-hydrides: the Ti(iii)-H in homogeneous olefin polymerization. [PDF]
Chem Sci, 2020 Salvadori E +3 more
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Recent Developments in Olefin Polymerization Catalysts
, 1990 Kazuo Soga, Takeshi Shiono
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Masked Silylenes: Controlled Generation and Reactivity Under Thermal and Equilibrium Conditions
European Journal of Inorganic Chemistry, EarlyView.This Review provides an overview of masked silylenes as bench‐stable precursors that release silylenes (R2Si:) under thermal activation or reversible equilibria. Precursor preparation, generation pathways, and characteristic reactivity are summarized, including trapping chemistry, reversible interconversions, insertion‐type processes, and small ...
Kei Ota, Kanata Miyahara, Norio Nakata
wiley +1 more source
The structure and reactivity of supported Ziegler-Natta catalysts in olefin polymerization
, 1997 N. Yu. Kovaleva +2 more
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European Journal of Inorganic Chemistry, EarlyView.Gold nanoparticles supported on poly(2,6‐dimethyl‐1,4‐phenylene oxide) (AuNPs‐PPO) demonstrates efficient and selective hydroamination, with performance tuned by reaction conditions and substrate design. Electron‐withdrawing substituents enhance conversion while preserving E‐imine selectivity, highlighting a key role of intermediate acidity.
Marta Aversa +8 more
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Research Progress in Precision Polymerization of Polar Olefin Monomers by Lewis Pairs★ [PDF]
, 2023 Yi Wan, Jianghua He, Yuetao Zhang
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Push–Pull Ynamines and Push–Pull Ynamides: Synthesis, Structure, Reactivity, and Application
European Journal of Organic Chemistry, EarlyView.Push–pull ynamines and push–pull ynamides, which carry an EWG and an amino or amido group as EDG, are highly interesting classes of EDG‐EWG alkynes that have been intensively studied due to their exceptional reactivity. In this review, the synthesis, structure, reactivity, and application of push–pull ynamines, push–pull ynecarbamates, push–pull ...
Hans‐Joachim Gais
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