Results 81 to 90 of about 17,166 (245)

Vanadium(V) oxo and imido calix[8]arene complexes: synthesis, structural studies, and ethylene homo/copolymerisation capability [PDF]

, 2015
Interaction of p-tert-butylcalix[8]areneH₈ (L⁸H₈) with in-situ generated [NaVO(Ot-Bu)₄] (from VOCl₃ and four equivalents of NaOtBu) afforded the dark brown complex [Na(NCMe)₅][(VO)₂L⁸H]·4MeCN (1·4MeCN), in which the calix[8]arene adopts a saddle-shaped ...
Elsegood, Mark R. J., Jiang, Chengying, Lee, Darren S., Michiue, Kenji, Redshaw, Carl, Walton, Mark J.   +5 more
core   +2 more sources

Biofilm‐Antagonist Ginger‐Based 3D‐Printable Photoresins for Complex Implant Designs Exhibiting Advanced Multifunctional Biomedical Applications

Advanced Materials, EarlyView.
This work offers unique Ginger‐based 3D‐printable resins that can print customizable high‐resolution complex designs. The customizable printing backbone of Zingerol prints also mimics various human bones' strength. Acquisition of in‐vivo biocompatibility in rat model with no severe inflammatory response, along with in‐vitro antioxidant and ex‐vivo anti‐
Simran Jindal, Majd Bisharat, Bassma Khamaisi, Krishanu Ghosal, Eid Nassar‐Marjiya, Qi Wu, Shadi Daoud, Idan Redenski, Samer Srouji, Shady Farah   +9 more
wiley   +1 more source

Mixed‐Metal Promotion in a Manganese‐Molybdenum Oxynitride as Catalyst to Integrate C─C and C─N Coupling Reactions for the Direct Synthesis of Acetonitrile from Syngas and Ammonia

Advanced Materials, EarlyView.
Transition metal oxy/carbo‐nitrides show great promise as catalysts for sustainable processes. A Mn‐Mo mixed‐metal oxynitride attains remarkable performance for the direct synthesis of acetonitrile, an important commodity chemical, via sequential C─N and C─C coupling from syngas (C1) and ammonia (N1) feedstocks.
M. Elena Martínez‐Monje, Wilson Henao, Tania Rodenas, Patricia Concepción, Virginia Pérez Dieste, Alexander Missyul, Giovanni Agostini, Gonzalo Prieto   +7 more
wiley   +1 more source

"Effects of different vulcanization systems on properties of bio-based poly（di-n-butyl itaconate-co-butadiene) rubber"

Hecheng xiangjiao gongye
The effects of conventional vulcanization （CV) system, semi-effective vulcanization （SEV) system, effective vulcanization （EV) system, peroxide 1,3-bis（tert-butylperoxyisopropyl) benzene （BIBP)/triallyl isocyanurate （TAIC) vulcanization system, and ...
HAN Ju1,2, HAO Fu-lan1,2, ZHAO Chun-cai1,2, NIU Chun-liang1,2, ZHENG Hong-bing1,2
doaj   +1 more source

Kinetic resolution of racemic {alpha}-olefins with ansa-zirconocene polymerization catalysts: Enantiomorphic site vs. chain end control [PDF]

, 2006
Copolymerization of racemic {alpha}-olefins with ethylene and propylene was carried out in the presence of enantiopure C1-symmetric ansa metallocene, {1,2-(SiMe2)2({eta}5-C5H-3,5-(CHMe2)2)({eta}5-C5H3)}ZrCl2 to probe the effect of the polymer chain end ...
Bercaw, John E., Byers, Jeffery A.
core   +1 more source

Characterization and Dynamics of Substituted Ruthenacyclobutanes Relevant to the Olefin Cross-Metathesis Reaction [PDF]

, 2011
The reaction of the phosphonium alkylidene [(H_(2)IMes)RuCl2═CHP(Cy)_3)]^(+) BF_(4)^− with propene, 1-butene, and 1-hexene at −45 °C affords various substituted, metathesis-active ruthenacycles. These metallacycles were found to equilibrate over extended
Blake, Garrett, Grubbs, Robert H., VanderVelde, David G., Wenzel, Anna G.   +3 more
core   +2 more sources

Crystal Engineering of Reticular Materials for Gas‐ and Liquid‐Phase Hydrocarbon Separation

Advanced Materials, EarlyView.
Crystal engineering enables systematic study of structure/function relationships as exemplified by pore engineering of reticular sorbents, including porous coordination networks and covalent organic frameworks. This review assesses such studies applied across the full scope of industrially relevant hydrocarbon separations to provide insight into how ...
Xia Li, Soumya Mukherjee, Michael J. Zaworotko   +2 more
wiley   +1 more source

Silicoaluminates as “support activator” systems in olefin polymerization processes [PDF]

, 2010
In this work we report the polymerization behaviour of natural clays (montmorillonites, MMT) as activating supports. These materials have been modified by treatment with different aluminium compounds in order to obtain enriched aluminium clays and to ...
Alba Carranza, María Dolores, Carmejo, C., Cuenca, T., Tabernero, Vanessa, Terreros, P.   +4 more
core   +2 more sources

In Situ Amine Formation to Modulate MOF‐Derived PdIn N‐Doped Carbon Catalysts

Advanced Materials, EarlyView.
An amine‐assisted approach converts PdIn‐MOF into PdIn intermetallic nanoparticles embedded in N‐doped carbon. In situ‐generated amines trigger early Pd nucleation, producing smaller PdIn domains than direct pyrolysis. Amine sterics and basicity tune composition and particle size, while solvent and amine co‐determine textural features.
Gonzalo Egea, Jordan Santiago Martinez, M. Asunción Molina, Jaime Mazarío, Lucy Costley‐Wood, Christian Cerezo‐Navarrete, Carlo Marini, Eduardo Villalobos‐Portillo, Andrew M. Beale, Pascual Oña‐Burgos   +9 more
wiley   +1 more source

Late Transition Metal Olefin Polymerization Catalysts Derived from 8-Arylnaphthylamines

Inorganics
Late transition metal catalysts represent a significant class of olefin polymerization catalysts that have played an essential role in advancing the polyolefin industry owing to their highly tunable ligands and low oxophilicity.
Zonglin Qiu, Wenyan Wang, Handou Zheng, Dengfei Wang, Xinglong Zhao, Guangshui Tu, Jiahao Yang, Haiyang Gao   +7 more
doaj   +1 more source