Results 141 to 150 of about 3,088 (203)

The Role of Charge Transfer and Linker States in the Magnetoluminescence of a Diradical With Two Spatially Proximate Triarylmethyl Units

Advanced Optical Materials, EarlyView.
Magnetoluminescent (ML) diradicals exhibit field‐dependent emission due to magnetic field‐dependent spin state populations and spin‐dependent emission properties. In this work, quantum chemical calculations applied to the first reported ML diradical provide evidence of the different deactivation pathways of the excited singlet and triplet states and ...
Fatemeh Mamusi, Jordi Ribas‐Ariño, Mercè Deumal, Maria Fumanal   +3 more
wiley   +1 more source

High Efficiency 3‐Tandem Top Emitting Pure‐Blue OLEDs Beyond the BT.2020 Blue Standard

Advanced Optical Materials, EarlyView.
We report a high‐efficiency ultrapure‐blue 3‐tandem TEOLED through synergistic optimization of a narrowband MR‐TADF emitter, Purcell‐based cavity design, and pure Ag cathode/CPL structure. The optimized device achieves 463 nm emission, an ultranarrow FWHM of 10 nm, CIE y of 0.040, and a blue index of 1,596 cd/A/y, surpassing the BT.2020 blue standard ...
Jun Hyeog Oh, Se Chan Cha, Hyunmin Cho, Hyeong Geun Jo, Nisha Vergineya S, Jang Hyuk Kwon   +5 more
wiley   +1 more source

Engineering Energy Harvesting Pathways in Mn‐Yb‐Doped Perovskite Nanocrystals

Advanced Optical Materials, EarlyView.
Mn‐Yb codoping in metal halide perovskite nanocrystals establishes dual‐channel energy reservoirs that capture charge carriers and drip‐feed them back to the host on millisecond timescales. This synergistic recycling mechanism overcomes prompt nanosecond recombination limitations, enabling an eight‐fold enhancement in photocatalytic CO2​ reduction ...
Manoj Sharma, Chang Cao, Pria Ramkissoon, Hanchen Li, Nadine J. Schrenker, Naufan Nurrosyid, Anthony S. R. Chesman, Junhong Yu, Joanne Etheridge, Trevor A. Smith, Akshat Tanksale, Jacek. J. Jasieniak   +11 more
wiley   +1 more source

Plasmon‐Induced Optothermal Manipulation of Colloidal Particles and Biological Entities Resilient to Saline Environments

Advanced Optical Materials, EarlyView.
The particle with high surface hydrophilicity exhibits strong thermophoretic attraction, as its dense hydration layer enhances the role of interfacial water molecules in determining thermophoretic mobility over other ionic effects. This finding elucidates the mechanism underlying the robust thermophoretic accumulation of Escherichia coli in high ...
Seungyeop Kang, Louis Quaire‐‐Merlin, Alex J. Thompson, Jang Ah Kim   +3 more
wiley   +1 more source

Modeling Light‐Induced Synaptic Behavior and Visual Memory of Azopolymeric Compounds

Advanced Optical Materials, EarlyView.
In the framework of neuromorphic hardware it is essential to predict the evolution of the internal state of the devices mimicking synaptic functionalities to perform in‐silico modeling of specific computational tasks. Here, we provide a rate‐balance equation model to describe the synaptic‐like response of light‐actuated azopolymeric compounds and ...
Mateo Rosero‐Realpe, Federico Ferrarese Lupi, Gianluca Milano, Angelo Angelini   +3 more
wiley   +1 more source

Single‐Layer Cholesteric Liquid Crystal Polymer Films With Visible Broadband Reflection

Advanced Optical Materials, EarlyView.
A single‐layer spin‐coated cholesteric liquid crystal polymer film exhibiting broadband reflection across the visible spectrum is demonstrated. By controlling photopolymerization‐induced pitch‐gradient formation, the film achieves low‐scattering broadband reflection, circular polarization selectivity, and compatibility with photolithographic patterning
Po‐Chun Shih, Yu‐Ming Huang, Chun‐Ting Chen, Kuan‐Wu Lin, Cheng‐Chang Li, Chun‐Ta Wang   +5 more
wiley   +1 more source

White Light Emission and Energy Transfer in Mixed‐Metal Europium/Terbium/Thulium Formate Metal–Organic Frameworks: Effect of Lanthanum Dilution

Advanced Optical Materials, EarlyView.
A series of Eu3+, Tb3+, Tm3+ and La3+ formate‐based (mixed)metal‐organic frameworks were synthesized and investigated for energy transfer and white‐light emission. Efficient Tb3+→Eu3+ transfer enabled tuneable luminescence, while Tm3+ incorporation afforded near‐white emission.
Leonardo E. Cruz‐Estrada, Irvin D. Villar‐Gutiérrez, Giuliano Giambastiani, Ciro Falcony, Silvia E. Castillo‐Blum, Andrea Rossin   +5 more
wiley   +1 more source

MANGO‐“Fruitcage”: A Conditional Photocage Utilizing a Fluorescence Light‐Up Aptamer

Advanced Optical Materials, EarlyView.
Fruitcaging ‐ a proof of concept study of a conditional photocage (Thiazol‐Orange) activated upon binding to the fluorescence light up aptamer (Mango). The prolongation of the excited state lifetime explains the redirection of the reactive pathway toward photocleavage and provides a sensitive spectroscopic readout.
Konstantinos Stamatakis, Nina Kaltenschnee, Francesco A. Greco, Marko Mitrović, Stefan Knapp, Alexander Heckel, Josef Wachtveitl   +6 more
wiley   +1 more source

Microcone Array‐Mediated Distance Tuning for Photonic Nanojet‐Amplified SERS

Advanced Optical Materials, EarlyView.
A tunable microcone array platform provides precise vertical gap control between dielectric microspheres and a SERS‐active surface. This structural regulation aligns the photonic nanojet focal point with plasmonic hotspots, delivering a 15‐fold optical signal enhancement.
Chen‐Ting Hung, Yan‐Ru Liu, Ko‐Chi Chen, You‐Chia Chang, Yuh‐Lin Wang, Yih‐Fan Chen   +5 more
wiley   +1 more source

Lead‐Free Chiral Hybrid Metal Halides for Circularly Polarized Light‐Emitting Diodes

Advanced Optical Materials, EarlyView.
Lead‐free chiral hybrid metal halides provide a versatile platform for realizing chiroptical responses through chiral modulation of metal–halide frameworks with diverse dimensionalities, induces inversion‐symmetry breaking and enables dissymmetric excited‐state transitions toward efficient circularly polarized luminescence and electroluminescence. This
Kun Zhu, Li Wan
wiley   +1 more source