Results 141 to 150 of about 363,858 (234)

Exploring the Boundaries of Aromaticity in Complex Structures and Excited States Through Computational Analysis

open access: yesChemistry – A European Journal, EarlyView.
Understanding aromaticity has evolved from benzene‐centric concepts to a broad multidimensional framework spanning organic, inorganic, and excited‐state systems. This review highlights ambiguities between magnetic, electronic, geometric, and energetic descriptors, emphasizing the need for unified, multi‐criteria approaches.
Sílvia Escayola   +2 more
wiley   +1 more source

Orbital - Vol. 4 No. 4 - October-December 2012 [PDF]

open access: yes, 2013
Production, Orbital, Orbital Production
core  

Vibrational Circular Dichroism Spectra of 2,5‐Diaminoterephtalate Macrocycles Reveal Distant Vibrational Exciton Coupling

open access: yesChemistry – A European Journal, EarlyView.
The energy level diagrams for the ν(C═O) and the δ(N─H) vibrations, resulting of combining in‐phase and out‐of‐phase modes on the basis of their local symmetries, was built by applying the exciton coupling theory to a new class of chiral macrocycles, based on the 2,5‐diaminoterephthalate scaffold.
Samara Medina   +4 more
wiley   +1 more source

Hydrogen Release From Silicon─Hydrogen Systems: From Surface Chemistry to Higher‐Coordinate Molecular Mechanisms

open access: yesChemistry – A European Journal, EarlyView.
Hydrogen‐release processes in silicon chemistry occur across a broad spectrum of systems, including crystalline silicon surfaces, nanoporous materials, Zintl phases, and molecular hydrides. This Review highlights how Si─H activation and H2 evolution are governed by structure, coordination environment, and dynamic access to reactive geometries, with ...
Robin Rothfelder, Jonathan O. Bauer
wiley   +1 more source

Orbital apex inflammation: a curious case of COVID-19. [PDF]

open access: yesDigit J Ophthalmol, 2022
Hussain A   +5 more
europepmc   +1 more source

Reversible Assembly and Disassembly of σ‐Aromatic B3 Rings

open access: yesChemistry – A European Journal, EarlyView.
B3 rings are the smallest σ‐aromatic boron compounds. Here, we show for the first time that cationic diboranes with an electron‐precise (2c,2e) bond can be reversibly converted to σ‐aromatic B3 rings with electron‐deficient (3c,2e) bonding. Base‐induced disassembly of the B3 ring leads back to cationic diboranes and monoborane adducts.
Julian Krauß   +4 more
wiley   +1 more source

Home - About - Disclaimer - Privacy