Dual‐state activation of singlet and triplet excitons is achieved in perylene‐based nanomicelles via donor engineering. By synergistically pairing charge transfer with energy transfer pathways, while concurrently enabling pollutant pre‐enrichment, this strategy establishes spatial coupling between efficient ROS generation and rapid mineralization ...
Chenfan Xie +8 more
wiley +1 more source
Observation of van der Waals resonances in low-energy F + H<sub>2</sub>(<i>v</i> = 0, <i>j</i> = 1) reaction. [PDF]
Wang H +9 more
europepmc +1 more source
The Preparatory (Anti)Bonding Character of Molecular Orbitals
Herein, a concept to qualitatively predict changes in bond dissociation energies upon reduction or oxidation of molecular compounds is introduced. Changing the population of so‐called preparatory molecular orbitals influences how molecular fragments are relaxing after bond cleavage, which is shown for isolated organometallic aluminum compounds as well ...
Jonas O. Wenzel +10 more
wiley +1 more source
Structural and Spectroscopic Characterization of Two Nitropyridine Amino <i>N</i>-Oxide Derivatives. [PDF]
Godlewska P +6 more
europepmc +1 more source
Emergent 3D Fermiology and Magnetism in an Intercalated Van der Waals System
An emergent three‐dimensional electronic state is uncovered in an intercalated van der Waals system. A spin‐polarized intercalant‐host hybridized band crossing the Fermi level provides an itinerant channel for interlayer exchange, highlighting how electronic dispersion governs magnetic dimensionality.
Luigi Camerano +18 more
wiley +1 more source
Quantum state-to-state reaction dynamics of F + HD → HF + D via a single partial wave shape resonance state. [PDF]
Yuan D +13 more
europepmc +1 more source
Coordination‐Tuned Iridium Single‐Atom Nanozymes Boost Multienzyme Activity for Colorimetric Sensing
Breaking the coordination symmetry of Ir single‐atom sites through asymmetric Ir–N3S1 engineering tailors interfacial electron transfer, oxygen activation, and multienzyme‐like catalytic pathways. Operando spectroscopy and theoretical modeling uncover the atomic‐level origin of activity enhancement, providing a strategy for designing multifunctional ...
Tao Li +10 more
wiley +1 more source
A dianionic allene bound to vanadium(iii) enables interconversion between vanadatetrahedranes, vanadacyclobutadienes and deprotiovanadacyclobutadienes. [PDF]
Russell JB +8 more
europepmc +1 more source
High‐Temperature Persistent Luminescence and Anti‐Thermal Quenching in LiGa5O8 by Trap Engineering
Cu/Zn co‐doping creates deep and thermally stable traps in LiGa5O8, enabling enhanced high‐temperature persistent luminescence, anti‐thermal‐quenching emission, and dynamic blue‐to‐red color evolution. ABSTRACT High‐temperature luminescent materials are essential for applications in displays, information storage, anti‐counterfeiting, and extreme ...
Yuchen Wang +11 more
wiley +1 more source

