Results 1 to 10 of about 3,337,706 (304)
The Evolution of Data-Driven Modeling in Organic Chemistry. [PDF]
Organic chemistry is replete with complex relationships: for example, how a reactant’s structure relates to the resulting product formed; how reaction conditions relate to yield; how a catalyst’s structure relates to enantioselectivity.
Williams WL +5 more
europepmc +2 more sources
Solute-Solvent Interactions in Modern Physical Organic Chemistry: Supramolecular Polymers as a Muse. [PDF]
Interactions between solvents and solutes are a cornerstone of physical organic chemistry and have been the subject of investigations over the last century.
Mabesoone MFJ, Palmans ARA, Meijer EW.
europepmc +2 more sources
On the Use of Iron in Organic Chemistry. [PDF]
Guðmundsson A, Bäckvall JE.
europepmc +3 more sources
Summary: Trifluoromethylated molecules have gained privileged recognition among the medicinal and pharmaceutical chemists. Sustainable photoredox- and electrochemical processes were employed to facilitate the relatively less explored radical cross ...
Muhammad Awais Ashraf +4 more
doaj +1 more source
Homologation of aryl ketones to long-chain ketones and aldehydes via C–C bond cleavage
Summary: Transition metal-catalyzed C–C bond cleavage is a powerful tool for the reconstruction of a molecular skeleton. We report herein the multi-carbon homologation of aryl ketones to long-chain ketones and aldehydes via ligand-promoted Ar−C(O) bond ...
Xing Wang +4 more
doaj +1 more source
Water as the reaction medium in organic chemistry: from our worst enemy to our best friend
A review presenting water as the logical reaction medium for the future of organic chemistry. A discussion is offered that covers both the “on water” and “in water” phenomena, and how water is playing unique roles in each, specifically with regard to its
M. Cortes‐Clerget +5 more
semanticscholar +1 more source
Copper-mediated aerobic trifluoromethyltelluration of boronic acids with [Me4N][TeCF3]
Summary: A copper-mediated trifluoromethyltelluration of arylboronic acids with [Me4N][TeCF3] using air as an environmental friendly oxidant is presented. The reaction proceeded smoothly under mild conditions in the presence of Cu(OTf)2 and bipyridine to
Jing-Yan Dong +3 more
doaj +1 more source
Summary: A concise copper-catalyzed oxidative dehydrogenative dearomatization of indole derivatives for the direct synthesis of spirocyclic indolenines containing fluorene and indeno[2,1-b]indole groups has been established.
Junli Chao +6 more
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Fluorinated tetrapodal anion transporters
Summary: Synthetic anion transporters show potential in treating life-threatening diseases like cystic fibrosis and cancer. However, with increasingly complex transporter architectures designed to control anion binding and transport, it is important to ...
Alexander M. Gilchrist +4 more
doaj +1 more source
The serendipitous effect of KF in Ritter reaction: Photo-induced amino-alkylation of alkenes
Summary: Ritter reaction has been recognized as an elegant strategy to construct the C−N bond. Its key feature is forming the carbocation for nucleophilic attack by nitriles.
Yu-Qing Guan +6 more
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