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Physical organic chemistry [PDF]
Beilstein Journal of Organic Chemistry, 2010 Physical organic chemistry – the study of the interplay between structure and reactivity in organic molecules – underpins organic chemistry, and we cannot imagine organic chemistry as a subject without knowledge of mechanism and reactivity. It is sometimes thought that the golden age of ‘physical organic chemistry’ was in the 20th century, when ...
John A. Murphy
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On the Use of Iron in Organic Chemistry. [PDF]
Molecules, 2020 Guðmundsson A, Bäckvall JE.
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iScience, 2021 Summary: Trifluoromethylated molecules have gained privileged recognition among the medicinal and pharmaceutical chemists. Sustainable photoredox- and electrochemical processes were employed to facilitate the relatively less explored radical cross ...
Muhammad Awais Ashraf +4 more
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Homologation of aryl ketones to long-chain ketones and aldehydes via C–C bond cleavage
iScience, 2022 Summary: Transition metal-catalyzed C–C bond cleavage is a powerful tool for the reconstruction of a molecular skeleton. We report herein the multi-carbon homologation of aryl ketones to long-chain ketones and aldehydes via ligand-promoted Ar−C(O) bond ...
Xing Wang +4 more
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Fluorinated tetrapodal anion transporters
iScience, 2023 Summary: Synthetic anion transporters show potential in treating life-threatening diseases like cystic fibrosis and cancer. However, with increasingly complex transporter architectures designed to control anion binding and transport, it is important to ...
Alexander M. Gilchrist +4 more
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Copper-mediated aerobic trifluoromethyltelluration of boronic acids with [Me4N][TeCF3]
iScience, 2022 Summary: A copper-mediated trifluoromethyltelluration of arylboronic acids with [Me4N][TeCF3] using air as an environmental friendly oxidant is presented. The reaction proceeded smoothly under mild conditions in the presence of Cu(OTf)2 and bipyridine to
Jing-Yan Dong +3 more
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iScience, 2022 Summary: A concise copper-catalyzed oxidative dehydrogenative dearomatization of indole derivatives for the direct synthesis of spirocyclic indolenines containing fluorene and indeno[2,1-b]indole groups has been established.
Junli Chao +6 more
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The serendipitous effect of KF in Ritter reaction: Photo-induced amino-alkylation of alkenes
iScience, 2021 Summary: Ritter reaction has been recognized as an elegant strategy to construct the C−N bond. Its key feature is forming the carbocation for nucleophilic attack by nitriles.
Yu-Qing Guan +6 more
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iScience, 2023 Summary: Unanticipated formation of symmetrical sulfonyl guanidine was observed while treating isonitriles with N,N-dibromoarylsulfonamides in absence of an external amine source.
Debashish Mishra +2 more
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