Results 21 to 30 of about 4,288,781 (386)
Copper-mediated aerobic trifluoromethyltelluration of boronic acids with [Me4N][TeCF3]
iScience, 2022 Summary: A copper-mediated trifluoromethyltelluration of arylboronic acids with [Me4N][TeCF3] using air as an environmental friendly oxidant is presented. The reaction proceeded smoothly under mild conditions in the presence of Cu(OTf)2 and bipyridine to
Jing-Yan Dong +3 more
doaj +1 more source
iScience, 2022 Summary: A concise copper-catalyzed oxidative dehydrogenative dearomatization of indole derivatives for the direct synthesis of spirocyclic indolenines containing fluorene and indeno[2,1-b]indole groups has been established.
Junli Chao +6 more
doaj +1 more source
The serendipitous effect of KF in Ritter reaction: Photo-induced amino-alkylation of alkenes
iScience, 2021 Summary: Ritter reaction has been recognized as an elegant strategy to construct the C−N bond. Its key feature is forming the carbocation for nucleophilic attack by nitriles.
Yu-Qing Guan +6 more
doaj +1 more source
iScience, 2023 Summary: Unanticipated formation of symmetrical sulfonyl guanidine was observed while treating isonitriles with N,N-dibromoarylsulfonamides in absence of an external amine source.
Debashish Mishra +2 more
doaj +1 more source
iScience, 2020 Summary: Over the past decades, asymmetric catalysis has been intensely investigated as a powerful tool for the preparation of numerous chiral biologically active compounds.
Huamin Wang +3 more
doaj +1 more source
Selective Quadruple C(sp3)-F Functionalization of Polyfluoroalkyl Ketones
iScience, 2020 Summary: The significance of organofluorine compounds has inspired the establishment of numerous methods for the functionalization of rather inert C-F bonds.
Ting Xie +7 more
doaj +1 more source
Further developments of β,γ-unsaturated α-ketoesters as versatile synthons in asymmetric catalysis
iScience, 2022 Summary: β,γ-Unsaturated α-ketoesters prove to be versatile organic synthons participating in diverse catalytic asymmetric transformations with the breathtaking development of organo-catalysis, new catalytic systems including ingenious chiral ligands as ...
Ruixian Deng +4 more
doaj +1 more source
iScience, 2022 Summary: The three-center-four-electron halogen bond (3c4e X-bond) presents a fundamental design concept for catalysis. By integrating halogen(I) (X+: I+ or Br+), the bis-pyridyl ligand NN, and a non-nucleophilic counteranion Y, we developed non-metallic
Shunya Oishi +6 more
doaj +1 more source
Turing patterns by supramolecular self-assembly of a single salphen building block
iScience, 2022 Summary: In the 1950s, Alan Turing showed that concerted reactions and diffusion of activating and inhibiting chemical species can autonomously generate patterns without previous positional information, thus providing a chemical basis for morphogenesis ...
Martha V. Escárcega-Bobadilla +3 more
doaj +1 more source
Reticular Chemistry for Highly Porous Metal-Organic Frameworks: The Chemistry and Applications.
Accounts of Chemical Research, 2022 ConspectusCurrent global crises related to clean energy and the environment entail the development of materials that are capable of addressing these challenges.
Zhijie Chen +3 more
semanticscholar +1 more source