The Importance of Metal‐Organic Framework Linker Atoms for CO2 Reduction: A DFT Study
Using DFT, we examine the role of linker atoms in CO2 reduction on copper‐based metal organic frameworks (Cu MOFs). Our calculations reveal that linker atoms may serve as both CO2 and H‐shuttling sites and suggest linker electrostatics as a descriptor for linker activity. ABSTRACT Although the metal within the secondary building unit of a metal‐organic
Ugochukwu Nwosu, Samira Siahrostami
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Molecular and biophysical foundations of nano-enabled seed priming and smart nanocarriers for crop stress alleviation. [PDF]
Abdulbaki AS +3 more
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Iron‐Mediated Release of Aged Dissolved Organic Carbon From Waterlogged Peatland Under Warming
This study conducts a five‐year in situ warming experiment in high‐altitude peatlands to examine dissolved organic carbon (DOC) release. The study shows that warming promotes the release of plant‐derived modern DOC in drained peatlands, but amplifies aquatic export of century‐old DOC from waterlogged peatlands via Fe‐mediated DOC mobilization—a ...
Guohua Dai +18 more
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Nanotechnology for Radionuclide and Heavy Metal Removal in Mining-Impacted Water Systems: Advances, Challenges, and Future Directions. [PDF]
Selala LG, Sithole T, Rathebe PC.
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Electrolyte Additive Strategies in Aqueous Zn‐Ion Batteries: Recent Advances and Prospects
This article provides a comprehensive overview of the current status and future development directions of AZIBs electrolyte additives in three aspects: stabilizing zinc anodes (uniform deposition, inhibition of dendritic crystals), protecting cathodes (structural stability, inhibition of dissolution), and enhancing electrolyte stability (wider ...
Yuanze Yu +7 more
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Rhizosphere microbes are partners in plant stress adaptation. [PDF]
Araujo ASF +3 more
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L‐cysteine‐configured chiral polyurethane nanoparticles suppress ocular inflammation and reduce extracellular matrix (ECM) degradation in ectopia lentis by regulating macrophages polarization and inhibiting nuclear factor kappa B signaling pathway. By promoting zonular fiber‐associated protein restoration and tissue repair, this minimally invasive ...
Yinuo Wen +17 more
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Ammonification Process Is Limited by Transformation of Medium Molecular Weight Nitrogenous Organics but Not Hydrolysis of Proteins. [PDF]
Li J, Qiu J, Lü F, Zhang H, He P.
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A multifunctional HA‐conjugated nanoplatform (HA‐PGMC) integrates CuO2, glucose oxidase, and mil‐100 to enable cascade catalytic ROS generation in tumor microenvironments. This self‐supplying ROS strategy induces immunogenic cell death, reprograms “cold” tumors into “hot” ones, and synergizes with PD‐L1 blockade, achieving potent chemodynamic ...
Man Lung Lee +6 more
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Redox chemistry, catalysis, and electrochemical detection of periodate species: sensors, mechanisms, and applications in green chemistry. [PDF]
Alrajhi R +3 more
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