In situ generation of Mes2Mg as a non-nucleophilic carbon-centred base reagent for the efficient one-pot conversion of ketones to silyl enol ethers [PDF]
, 2008 Treatment of commercially available MesMgBr with 1,4-dioxane produces the key Mes2Mg reagent in situ which then mediates the deprotonation of ketones to deliver trimethylsilyl enol ethers, at readily accessible temperatures and without any nucleophilic ...
Hayes, Douglas. +2 more
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Organometallic and Bioorganometallic Chemistry - Ferrocene and Metal Carbonyls [PDF]
Kemija u Industriji, 2011 Organometallic chemistry deals with compounds containing metal-carbon bonds. Basic organometallics derived from the s- and p-block metals (containing solely σ-bonds) were understood earlier, while organometallic chemistry of the d- and f-block has ...
Čakić Semenčić, M., Rapić, V.
doaj
Fundamental organometallic reactions: Applications on the CYBER 205 [PDF]
, 1984 Two of the most challenging problems of Organometallic chemistry (loosely defined) are pollution control with the large space velocities needed and nitrogen fixation, a process so capably done by nature and so relatively poorly done by man (industry ...
Rappe, A. K.
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Formation and characterization of inorganic membranes from zeolite-silica microcomposites [PDF]
, 1988 Small crystals of zeolites (500-1000 nm) with two- and three-dimensional channel systems (faujasite and ZSM-5 structures) were embedded in amorphous thin films derived from TEOS hydrolyzed in alcoholic solution.
Barrer +6 more
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Hydrodenitrogenation of pyridines and quinolines at a multinuclear titanium hydride framework
Nature Communications, 2017 Hydrodenitrogenation is a fundamental process in the petroleum refinery context. Here, the authors report the mild ring-opening and denitrogenation of pyridines and quinolines with a titanium hydride cluster and the unusual formation of denitrogenated ...
Shaowei Hu +4 more
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Sensitivity of the photo-physical properties of organometallic complexes to small chemical changes
, 2010 We investigate an effective model Hamiltonian for organometallic complexes that are widely used in optoelectronic devices. The two most important parameters in the model are $J$, the effective exchange interaction between the $\pi$ and $\pi^*$ orbitals ...
Jacko, A. C. +2 more
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Nature CommunicationsCopolymerization of more activated methacrylates and less activated vinyl esters is challenging because of their large difference in reactivity ratio. This severely limits the development of high-performance materials.
Yi-Jie Ding +8 more
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iScience, 2020 Summary: Cisplatin (CDDP) has been a highly successful anticancer drug in cancer therapy; however, its further application suffers severe nephrotoxicity.
Runming Wang +8 more
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Isolable Geminal Bisgermenolates: A New Synthon in Organometallic Chemistry. [PDF]
Angew Chem Weinheim Bergstr Ger, 2021 Drusgala M +9 more
europepmc +2 more sources
Sol-gel incorporation of organometallic compounds into silica: useful precursors to metallic nanostructured materials [PDF]
, 2012 Indexación: Web of Science; ScieloLa inclusión del MLN organometálica = HOC 6 H 4 CH 2 CN • Mo (CO) 5 (6) en sílice amorfa con los precursores TEOS gelificante y N 3 P 3 {NH [CH 2 ] 3 Si [OEt] 3 } 6 permitirse los geles (MLN) ( SiO 2 ) n .
Aguirre, Pedro +3 more
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