Guanidinates as Alternative Ligands for Organometallic Complexes
For decades, ligands such as phosphanes or cyclopentadienyl ring derivatives have dominated Coordination and Organometallic Chemistry. At the same time, alternative compounds have emerged that could compete either for a more practical and accessible ...
Fernando Carrillo-Hermosilla +3 more
doaj +2 more sources
Review of Atypical Organometallic Compounds as Antimalarial Drugs
Organometallic compounds are molecules that contain at least one metal-carbon bond. Due to resistance of the Plasmodium parasite to traditional organic antimalarials, the use of organometallic compounds has become widely adopted in antimalarial drug ...
Samuel K. Kwofie +10 more
doaj +2 more sources
CO2 Electrochemical Reduction by Exohedral N-Pyridine Decorated Metal-Free Carbon Nanotubes
Electrochemical CO2 reduction reaction (CO2RR) to fuels and chemicals represents nowadays one of the most challenging solutions for renewable energy storage and utilization.
Giulia Tuci +7 more
doaj +1 more source
2D exfoliated black phosphorus influences healthy and cancer prostate cell behaviors
Nowadays, prostate cancer is the most widespread tumour in worldwide male population. Actually, brachytherapy is the most advanced radiotherapy strategy for the local treatment of prostate cancer.
Ines Fasolino +6 more
doaj +1 more source
In this study, we have developed innovative polymer nanocomposites by integrating magnesium-aluminum layered double hydroxide (LDH)-based nanocarriers modified with functional molecules into a fully biobased poly(lactic acid)/poly(butylene succinate-co ...
Francesca Cicogna +7 more
doaj +1 more source
Superconductivity in an organometallic compound [PDF]
Superconductivity with a T c of 3.6 K observed in K-doped o -TTB and the molecular arrangement of K-doped o -TTB.
Ren-Shu Wang +8 more
openaire +3 more sources
Organometallic half-sandwich iridium anticancer complexes [PDF]
The low-spin 5d6 IrIII organometallic half-sandwich complexes [(η5-Cpx)Ir(XY)Cl]0/+, Cpx = Cp*, tetramethyl(phenyl)cyclopentadienyl (Cpxph), or tetramethyl(biphenyl)cyclopentadienyl (Cpxbiph), XY = 1,10-phenanthroline (4−6), 2,2′-bipyridine (7−9 ...
Liu, Zhe +34 more
core +2 more sources
Organometallic iridium(III) anticancer complexes with new mechanisms of action: NCI-60 screening, mitochondrial targeting, and apoptosis [PDF]
Platinum complexes related to cisplatin, cis-[PtCl2(NH3)2], are successful anticancer drugs; however, other transition metal complexes offer potential for combating cisplatin resistance, decreasing side effects, and widening the spectrum of activity ...
Hands-Portman, Ian +5 more
core +1 more source
‘User-friendly’ primary phosphines and an arsine: synthesis and characterization of new air-stable ligands incorporating the ferrocenyl group [PDF]
Reaction of FcCH₂CH₂P(O)(OH)₂ or FcCH₂P(O)(OH)(OEt) [Fc=Fe(η⁵-C₅H₄)(η⁵-C₅H₅)] with excess CH₂N₂ followed by reduction with Me₃SiCl–LiAlH₄ gives the air-stable primary phosphines FcCH₂CH₂PH₂ and the previously reported analogue FcCH₂PH₂ in high yields ...
Alley, Steven R., Henderson, William
core +1 more source
The Preparatory (Anti)Bonding Character of Molecular Orbitals. [PDF]
Herein, a concept to qualitatively predict changes in bond dissociation energies upon reduction or oxidation of molecular compounds is introduced. Changing the population of so‐called preparatory molecular orbitals influences how molecular fragments are relaxing after bond cleavage, which is shown for isolated organometallic aluminum compounds as well ...
Wenzel JO +10 more
europepmc +2 more sources

