Results 231 to 240 of about 84,401 (336)

Use of anethole-type ligands to design cytotoxic organometallic ruthenium compounds: An experimental and computational study

open access: green, 2019
Ricardo A. Delgado   +7 more
openalex   +2 more sources

On Phosphatitanacycles

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
Titanocene phosphinidenes react with terminal alkynes in formal [2 + 2] cycloadditions to give unsaturated [C2PTi] metallcycles. Diphosphene complexes in combination with aryl‐substituted alkynes react similarly to provide metallacyclopentenes. Titanocene‐phosphinidene and diphosphanediide (or diphosphene) complexes Cp2Ti(PMe3)PMesTer and Cp2Ti(P2Ar2) (
Andrey Petrov   +1 more
wiley   +1 more source

Anionic N‐Heterocyclic Carbene‐Based Silicon Halides with a Four‐Coordinated Silicon Atom

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
Silicon(IV) halides [{(Et3B)anIPr}SiHCl2] (4) and [{(Et3B)anIPr}SiBr3] (5) based on an anionic N‐heterocyclic carbene ligand (i.e., {(Et3B)anIPr} = (Et3B)C=C(H {N(Dipp)}2C, Dipp = 2,6‐iPr2C6H3) are reported. Silicon(IV) halides [{(Et3B)anIPr}SiHCl2] (4) and [{(Et3B)anIPr}SiBr3] (5) based on an anionic N‐heterocyclic carbene (NHC) ligand (i.e., {(Et3B ...
Henric Steffenfauseweh   +5 more
wiley   +1 more source

Scaffold Dependent Coordination Modes of Chelating PEP‐Type Ligands in Iron(0) Carbonyl Complexes (E = O, S)

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
The reaction of iron pentacarbonyl with various chelating diphosphine ligands containing oxygen or sulfur atoms in their backbone yields complexes that exhibit noteworthy coordination behavior. Depending on the natural bite angle of the ligands and the coordination behavior of the heteroatom, preferences regarding the coordination geometry are verified
Jonas Wohlrab   +3 more
wiley   +1 more source

Liquid jet capabilities for ultrafast chemistry at the SwissFEL Alvra instrument

open access: yesJournal of Synchrotron Radiation, EarlyView.
The technical aspects of the Alvra endstation are outlined and its scientific capabilities are demonstrated with commissioning results obtained during the early years of SwissFEL's operation.The Alvra experimental station at the Swiss X‐ray free‐electron laser, SwissFEL, investigates ultrafast dynamics in chemical and biological systems using X‐ray ...
Claudio Cirelli   +9 more
wiley   +1 more source

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