Results 141 to 150 of about 3,020 (171)
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Acetylcholinesterase mutants: oxime-assisted catalytic scavengers of organophosphonates.
Chemico-biological interactions, 2004instead abstract, part of the Introduction: Reaction of organophosphonates with acetylcholinesterase (AChE ; EC 3.1.1.7) is characterized by the formation of serine-conjugated adducts that are only slowly reversible. Since oximes are the only known antidote to nerve agent poisoning that restore the activity of AChE, mutagenesis of AChE should enable ...
Kovarik, Zrinka +4 more
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Fireproofing of polyurethane by organophosphonates
Journal of Thermal Analysis and Calorimetry, 2007International ...
Youssef, B. +3 more
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Heterocyclic Amine Derivatives of Zinc Organophosphonates
Chemistry of Materials, 2004A series of novel zinc(II) organophosphonates with coordinated 2,2‘-bipyridyl (2,2‘-bipy, C10H8N2) and 1,10-phenanthroline (phen, C12H8N2) ligands (with the proposed formulations: Zn(O3PC6H5)(C12H8N2), Zn2(O3PR)2(C12H8N2) (R = C6H5CH2, C2H5, CH3), and Zn2(O3PR)2(C10H8N2)(H2O) (R = C6H5, C6H5CH2)) has been prepared and characterized.
Rachael C. Clarke +3 more
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Microbial degradation of organophosphonates by soil bacteria
Microbiology, 2008Bacteria that can utilize glyphosate (GP) or methylphosphonic acid (MPA) as a sole phosphorus source have been isolated from soil samples polluted with organophosphonates (OP). No matter which of these compounds was predominant in the native habitat of the strains, all of them utilized methylphosphonate.
I T, Ermakova +2 more
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Bis(difluoroaluminum)organophosphonates and difluoroaluminumdiorganophosphinates
Journal of Polymer Science: Polymer Chemistry Edition, 1984AbstractOligomers and polymers of the general types [RR′P(O)OA1F2]n, I, and [F2AlOP(R)(O)OAlF2]n, II, were prepared by the addition of phosphonic or phosphinic acids and hydrogen fluoride to etherated alanes. The hydrocarbon moieties (R,R′) on the phosphonic and phosphinic acids were important determinants of physical and chemical properties.
Edward E. Flagg, Donald L. Schmidt
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Degradation of organophosphonates by Penicillium citrinum
Letters in Applied Microbiology, 1992Utilization of organophosphonates as the sole source of phosphorus, carbon or nitrogen by a soil isolate of Penicillium citrinum was studied. Penicillium citrinum was found to utilize 2-aminoethylphosphonic and 2-oxoalkylphosphonic acids as the sole phosphorus source whereas 1-hydroxyalkylphosphonates as well as 1-aminoalkylphosphonates and their ...
E. Zboińska +3 more
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Organophosphonic acids as drug candidates
Expert Opinion on Therapeutic Patents, 2006The discovery of phosphate mimetics that are suitable as drug candidates has been a challenging problem faced by medicinal chemists for many years. Several series of organophosphonic acids have been identified as phosphate mimetics and have resulted in multiple development candidates progressing to the clinic and even successfully reaching the market ...
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Radical-based dephosphorylation and organophosphonate biodegradation
Journal of the American Chemical Society, 1987Products resulting from the degradation of organophosphonates by Escherichia coli are identified and used as a basis for evaluating mechanisms which may be the chemical basis of the biodegradation. One mechanistic hypothesis which is consistent with the biodegradation products involves radical-based dephosphorylation.
J. W. Frost +3 more
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Organophosphonate derivatives of titanium and niobium alkoxoanions
Journal of Organometallic Chemistry, 1998The organophosphonate-substituted alkoxides [Bu4nN]2[{Ti(OMe)3(O3PPh)}2] (1) and [Bu4nN]2[{Nb(OMe)3(O3PPh)}2(μ-O)] (2) were prepd. from [Bu4nN][PhPO3H] and the metal alkoxides Ti(OMe)4 or Nb(OMe)5 resp. 1 And 2 were characterized by x-ray crystallog. (1·PhMe: monoclinic, space group C2, R = 0.0449; 2: monoclinic, space group P21/n, R = 0.0452).
Errington, R John +5 more
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Chapter 15. Metal Organophosphonate Proton Conductors
2011New ion conducting materials have major applications in new energy technologies. Foremost among these are applications as proton-conducting electrolyte membranes in hydrogen and direct methanol fuel cells and Li ion conductors for batteries. Significant challenges confront candidates for these membranes collectively, with the goal of better cost ...
George K. H. Shimizu +2 more
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