Nanoparticle Metal Oxides for Chlorocarbon and Organophosphonate Remediation
2007The nanotechnology revolution has affected many areas of science, including chemistry and chemical engineering. Although nanotechnology advances in electronics or in the manufacturing of nanomachines are rather recent developments, nanoscale chemical structures are much older.
Shyamala Rajagopalan+3 more
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Growth of Escherichia coli on some organophosphonic acids
Canadian Journal of Microbiology, 1969Escherichia coli (ATCC No. 8739) can use a variety of alkyl and aminoalkylphosphonic acids as a source of phosphorus during growth. Chloromethylphosphonate, phenylphosphonate, hydroxymethylphosphonate, and 2-aminoethylphosphonate will act as a source of phosphorus during growth in the absence of inorganic phosphate.
Stephen H. Bishop, Ashraf U. Alam
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Chapter 15. Metal Organophosphonate Proton Conductors
2011New ion conducting materials have major applications in new energy technologies. Foremost among these are applications as proton-conducting electrolyte membranes in hydrogen and direct methanol fuel cells and Li ion conductors for batteries. Significant challenges confront candidates for these membranes collectively, with the goal of better cost ...
Karl W. Dawson+2 more
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Photocatalytic decomposition of organophosphonates in irradiated TiO2 suspensions
Journal of Photochemistry and Photobiology A: Chemistry, 1997Abstract Kinetic analyses of the TiO 2 -catalyzed photodegradation of dimethyl methylphosphonate (DMMP) and diethyl methylphosphonate (DEMP) in oxygenated aqueous solutions are described. The effects of substrate concentration and solution pH are investigated.
Kevin E. O'Shea+5 more
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Crystal Chemistry of Organically Templated Vanadium Phosphates and Organophosphonates
ChemInform, 2003AbstractFor Abstract see ChemInform Abstract in Full Text.
Jon Zubieta+2 more
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Some bidentate amine adducts of indium(iii) organophosphonates
Journal of Materials Chemistry, 2001A series of indium(III) organophosphonates with coordinated 2,2′-bipyridyl and 1,10-phenanthroline ligands have been prepared and characterised. The bipyridyl and phenanthroline derivatives of indium(III) phenyl- and benzyl-phosphonates have a 1∶2∶1 molar ratio of metal∶phosphorus∶amine ligand, with proposed formulations In(O3PR)(O2P(OH)R)(C10H8N2)
Julia Morizzi+2 more
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Organophosphonates as anchoring agents onto metal oxide-based materials: synthesis and applications
, 2014Besides usual coupling agents such as, for instance, silane, thiol, or carboxylic acids, phosphonated-based low molecular weight molecules and polymers appear of great interest for the modification of metal oxides.
Rémi Boissezon+4 more
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Phosphonium ion fragmentation relevant to organophosphonate biodegradation
Journal of the American Chemical Society, 1989Microbial degradation of organophosphonates 1 via carbon to phosphorus (C-P) bond cleavage has prompted a rapid expansion in chemical literature relevant to the biodegradation. However, the chemistry of organophosphonates under reducing conditions, particularly in regard to C-P bond cleavage, is still largely unknown.
L. Z. Avila, John W. Frost
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Degradation of organophosphonic acids catalyzed by irradiated titanium dioxide
Journal of Photochemistry and Photobiology A: Chemistry, 1993Abstract The photoinduced decomposition of three organic phosphonic acids on irradiated titanium dioxide involves the cleavage of the carbon-phosphorus bond to generate the corresponding organic radical. Kinetic data for these reactions are consistent with the Langmuir-Hinshelwood model for heterogeneous reactions.
Jennifer Adamson+3 more
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Micromachined GC Columns for Fast Separation of Organophosphonate and Organosulfur Compounds
Analytical Chemistry, 2008This article demonstrates how to prepare microfabricated columns (microcolumns) for organophosphonate and organosulfur compound separation that rival the performance of commercial capillary columns. Approximately 16,500 theoretical plates were generated with a 3 m long OV-5-coated microcolumn with a 0.25 microm phase thickness using helium as the ...
Richard I. Masel+4 more
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