Results 41 to 50 of about 2,594 (171)

Thermal desorption of dimethyl methylphosphonate from MoO3 [PDF]

open access: yes, 2017
Organophosphonates are used as chemical warfare agents, pesticides, and corrosion inhibitors. New materials for the sorption, detection, and decomposition of these compounds are urgently needed.
Ashley R. Head   +29 more
core   +1 more source

New Wine in Old Bottles: Fully Substituted Arylthio Effect Realizes High‐Efficiency Purely Organic Phosphorescence Light‐Emitting Diode With Single and Ultra‐Stable Spectra Under 2000 cd m−2

open access: yesAggregate, Volume 6, Issue 4, April 2025.
Benefiting from the fully substituted arylthio effect, pure organic emitter 6S has the most obvious aggregation‐induced phosphorescence characteristic, the largest spin orbital coupling value, and the smallest the energy gap between S1 and T1. Consequently, a high maximum external quantum efficiency of 15.3% and ultra‐stable spectra under high ...
Baijun Zhang   +8 more
wiley   +1 more source

Pore-size tunable mesoporous zirconium organophosphonates with chiral (L)-proline for enzyme adsorption

open access: yes, 2007
Mesoporous zirconium organciphosphonates with a tunable mesopore (pore diameter: from 4.8 to 16.3 nm) were synthesized through co-condensation of ZrCl4 and 1-phosphomethylproline (H3PMP) with the aid of organic additives in the presence of an anionic ...
Li, Congming   +3 more
core   +1 more source

Effects of glyphosate on antibiotic resistance in soil bacteria and its potential significance: A review

open access: yesJournal of Environmental Quality, Volume 54, Issue 1, Page 160-180, January/February 2025.
Abstract The evolution and spread of antibiotic resistance are problems with important consequences for bacterial disease treatment. Antibiotic use in animal production and the subsequent export of antibiotic resistance elements in animal manure to soil is a concern.
Bradley L. Bearson   +4 more
wiley   +1 more source

Protection of water bodies from corrosion products and mineral deposits: selection of optimal inhibitors

open access: yesВодное хозяйство России: проблемы, технологии, управление
Enterprises in the chemical, metallurgical, petroleum and energy industries consume great amounts of water. Organizing of closed and drainless water supply systems enables to diminish expenses.
Afanasiy A. Protazanov   +2 more
doaj   +1 more source

Engineering a Mesoporous Silicon Nanoparticle Cage to Enhance Performance of a Phosphotriesterase Enzyme for Degradation of VX Nerve Agent

open access: yesAdvanced Science, Volume 11, Issue 48, December 26, 2024.
A porous silicon nanocage encapsulating phosphotriesterase variant L7ep‐3a is evaluated for nerve agent detoxification. By tuning the physicochemical properties of the enzyme–porous silicon nanoconstruct, enhanced catalytic activity, and operational stability are achieved compared to the free enzyme.
Yi‐Sheng Lu   +12 more
wiley   +1 more source

The Prospect of Selective Recognition of Nerve Agents with Modular Basket-like Hosts. A Structure-Activity Study of the Entrapment of a Series of Organophosphonates in Aqueous Media

open access: yes, 2013
We designed, prepared, and characterized three cup-shaped cavitands 1-3 for trapping organophosphonates (O=PR(OR')(2), 118-197 A3) whose shape and size correspond to G-type chemical warfare agents (132-186 A(3)).
Hadad, Christopher M.   +5 more
core   +1 more source

Mono‐Exponential Current Attenuation with Distance Across 16 nm Thick Bacteriorhodopsin Multilayers

open access: yesAdvanced Functional Materials, Volume 34, Issue 48, November 26, 2024.
Electronic charge transport through multilayers of the protein bacteriorhodopsin (bR) shows an intriguing, mono‐exponential conductance attenuation with layer thickness up to ≈16 nm. A measured small attenuation coefficient β ≈ 0.8 nm−1 indicates efficient long‐range transport, which is mostly limited by charge injection at the interfaces. Abstract The
Domenikos Chryssikos   +12 more
wiley   +1 more source

Synthesis of Mesostructured and Mesoporous Aluminum Organophosphonates Prepared by Using Diphosphonic Acids with Alkylene Groups

open access: yes, 2016
Mesostructured and mesoporous aluminum organophosphonates (AOPs) with 2-D hexagonal structures (AOP-2) can be synthesized by using alkylene diphosphonic acids in the presence of alkyltrimethylammonium (CnTMA) surfactants.
Tatsuo Kimura (2049088)
core   +1 more source

Catalytic Activation of Bis(2,2,2‐trifluoroethyl) Phosphite with Hf(IV) for the Synthesis of Mixed Dialkyl Phosphites

open access: yesAdvanced Synthesis &Catalysis, Volume 366, Issue 18, Page 3822-3828, September 17, 2024.
Abstract We developed a second generation of Lewis acid catalyst enabling selective and user‐friendly phosphonylation of diverse alcohols. This one‐pot method utilizes P(III) reagent bis(2,2,2–trifluoroethyl) phosphite under mild conditions. Exploring the influence of metal selection in Lewis acid catalysts revealed four highly active complexes for ...
Dario Mrdović   +2 more
wiley   +1 more source

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