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Rational Design of an Organotellurium Chalcogen Bonding Catalyst for Azetidine Activation.

Angewandte Chemie
The application of chalcogen bonding catalysis has been largely confined to benchmark reactions due to the limited structural diversity and activating ability of the catalysts, especially those derived from tellurium.
Fei Jiang   +4 more
semanticscholar   +1 more source

ChemInform Abstract: ORGANOTELLURIUMS. III. PREPARATION OF ALKYL HALIDES VIA ORGANOTELLURIUMS

Chemischer Informationsdienst, 1983
AbstractAus den Alkylhalogeniden (I) werden die Phenyltelluroalkane (III) hergestellt, die über die Tellur‐dihalogenide (IV) in die homologen Alkylhalogenide (V) übergeführt werden.
K. CHIKAMATSU   +3 more
openaire   +1 more source

Metal-metalloid bond containing complexes of bulky organotellurium ligand with palladium and ruthenium: applications in catalysis of C−O coupling and aldehyde to amide transformation reactions

New Journal of Chemistry, 2023
Anthracene-based ligand L1 comprising an imine functionality and a tellurium (Te) donor moiety has been prepared.
Preeti Oswal   +6 more
semanticscholar   +1 more source

Stabilisation of PVC with organotellurium compounds

Polymer Degradation and Stability, 1988
Abstract Organotellurium compounds are shown to behave similarly to organotin compounds as thermal and UV stabilisers for PVC. The most effective of these, the dialkyltellurium maleates, were, however, less effective than the corresponding tin compounds but the study points the way to further progress in the design of organometallic compounds as PVC ...
S.S. Abed-Ali, W.R. McWhinnie, G. Scott
openaire   +1 more source

Anodic Carboxylation and Sulfonylation of Organotellurium Compounds. Electrochemical Synthesis of Hypervalent Tellurium Compounds Bearing Te–O Bonds

Journal of the Electrochemical Society, 2023
Anodic oxidation of PhTeR (R = CF3CH2, CF2H, Me, Ph) was carried out in methanol containing various supporting electrolytes (YO− M+) such as p-tosylate, benzenesulfonate, acetate, and benzoate salts using a divided cell to provide the corresponding ...
T. Fujita, S. Inagi, T. Fuchigami
semanticscholar   +1 more source

SYNTHETIC APPLICATIONS OF ORGANOTELLURIUM CHEMISTRY

Phosphorus and Sulfur and the Related Elements, 1985
Abstract Newly developed applications of organotellurium chemistry, including carbon-carbon bond-forming reactions and functional group interconversions, are discussed.
openaire   +1 more source

Aspects of Organoselenium and Organotellurium Chemistry

Phosphorus, Sulfur, and Silicon and the Related Elements, 2005
The Chemistry of several condensed selenophenes, and tellurophenes (1–4) will be presented. The synthesis of mixed selenium-tellurium fulvenes (5) and generation of 2,4-bis-methyleneditelluretane (6) will be discussed.
M. V. Lakshmikantham   +3 more
openaire   +1 more source

Functionalized organotellurium macrocycles: tuning their optical bandgap and investigation of their catalytic activity.

Dalton Transactions
This work deals with the synthesis, characterization, and optical properties of 12-membered tellurium macrocycles functionalized with an allyl group.
Calvin Samuel   +4 more
semanticscholar   +1 more source

Organosulphur, organoselenium and organotellurium compounds for the development of heterogeneous and nanocatalytic systems for Suzuki coupling.

Dalton Transactions, 2022
Suzuki-Miyaura cross-coupling (SMC) is an extremely useful reaction in organic syntheses. During the last two decades, many researchers across the world have employed organochalcogen compounds in various ways for the development of catalytic systems for ...
Aayushi Arora   +6 more
semanticscholar   +1 more source

Addition of organotellurium trihalides to acetylenes

Organometallics, 1991
(p-Methoxyphenyl)tellurium trichloride reacts with terminal acetylenes to give 1-chloro-1-organyl-2-[dichloro(p-methoxyphenyl)telluro] ethenes of Z configuration in good yields. The Z stereochemistry of the addition products suggests that the reaction occurs through a four-centered cyclic transition state.
Joao V. Comasseto   +3 more
openaire   +1 more source

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