Results 81 to 90 of about 1,967 (213)

Mechanistic studies of organotellurium chemistry [PDF]

open access: yes, 1988
The oxidation of bis(p-ethoxyphenyl) ditelluride by hydrogen peroxide has been studied kinetically. The reaction monitored was an oxidation from tellurium(I) to tellurium(II). The reaction stoichiometry ratio was found to depend upon the initial reagent concentrations.
openaire   +1 more source

Isolation and molecular structures of novel organotellurium(IV) halides, oxyhalide and mixed halide

open access: yes, 2012
The formation of chiral (R)-[2-(4-ethyl-2-oxazolinyl)phenyl]tellurium(IV) trihalides (trichloride (5), tribromide (6) and triiodide (7)) and (R)-[2-(4-ethyl-2-oxazolinyl)phenyl]tellurium(II) bromide (8) is described.
RAKESH, P, SINGH, HB, BUTCHER, RJ
core   +1 more source

Photoinduced Switching from Living Radical Polymerization to a Radical Coupling Reaction Mediated by Organotellurium Compounds

open access: yes, 2016
An efficient and simple method for the synthesis of symmetric macromolecules by photoinduced switching from radical polymerization to a radical coupling reaction is reported.
Sora Tomita (2099158)   +3 more
core   +1 more source

Mechanism-Based Invention of High-Speed Living Radical Polymerization Using Organotellurium Compounds and Azo-Initiators

open access: yes, 2016
Kinetic analysis reveals the existence of two competing pathways in the organotellurium-mediated living radical polymerization (TERP) at elevated temperature.
Yungwan Kwak (1932946)   +6 more
core   +1 more source

Organotellurium Compounds as Novel Initiators for Controlled/Living Radical Polymerizations. Synthesis of Functionalized Polystyrenes and End-Group Modifications

open access: yes, 2016
Polymer-end mimetic organotellurium compounds initiate controlled/living radical polymerization of styrene derivatives that allows accurate molecular weight control with defined end-groups.
Shigeru Yamago (1325364)   +2 more
core   +1 more source

Novel organotin and organotellurium complexes : building blocks for new materials?

open access: yes, 2004
The research produced a series of novel oranotin and organotellurium compounds that are potential building blocks for new materials. In particular, one carbonate cluster has practical applications in the fixation and recovery of carbon dioxide gas from ...
Cassandra. Mitchell (13783570)
core  

Some Mechanistic Studies of Organotellurium Chemistry [PDF]

open access: yes
The work in this thesis is concerned with the mechanistic study of some organotellurium compounds, especially the diaryl-ditellurides. The effect of visible irradiation on the diaryl ditellurides in solution cantaining alcohol is described.
Mehdi, Raheem T.
core   +1 more source

Tailored Synthesis of Structurally Defined Polymers by Organotellurium-Mediated Living Radical Polymerization (TERP):  Synthesis of Poly(meth)acrylate Derivatives and Their Di- and Triblock Copolymers

open access: yes, 2016
The organotellurium-mediated living radical polymerization (TERP) method allows the synthesis of various polyacrylate and polymethacrylate derivatives with precise control of molecular weight and with defined end groups.
Shigeru Yamago (1325364)   +2 more
core   +1 more source

Kinetic Study on Role of Ditelluride in Organotellurium-Mediated Living Radical Polymerization (TERP)

open access: yes, 2016
The role of dimethyl ditelluride (MeTe)2 for the organotellurium-mediated living radical polymerizations (TERPs) of styrene (St) and methyl methacrylate (MMA) was kinetically studied.
Yungwan Kwak (1932946)   +4 more
core   +1 more source

Bcl-2 expression and apoptosis induction in human HL60 leukaemic cells treated with a novel organotellurium(IV) compound RT-04

open access: yes, 2008
Organotellurium(]V) compounds have been reported to have multiple biological activities including cysteine protease-inhibitory activity, mainly cathepsin B. As cathepsin B is a highly predictive indicator for prognosis and diagnosis of cancer, a possible
BINCOLETTO, C.   +9 more
core   +1 more source

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