Results 51 to 60 of about 2,761 (178)
The synthesis and spectral characterization of the novel organotin complexes [SnBu2(ten)] (1) and [SnBu2(Hten)(2)] (2) or the potent and widely used anti-inflammatory drug tenoxicam (H(2)ten) are reported. A crystal-structure determination of 1 showed that, in this complex, the ligand is doubly deprotonated at the hydroxy O-atom and the amide N atom ...
Demertzis, M. A. +4 more
openaire +2 more sources
Main Group Metals in Redox Catalysis
Main group metal redox catalysis is emerging as a credible alternative to transition metal chemistry. Elements from groups 13 to 15 now enable diverse catalytic manifolds, driven by ligand design and control of electronic structure. This review highlights recent advances, key design principles, and remaining challenges, positioning main group metals as
Olympia Mouriki +2 more
wiley +1 more source
ABSTRACT Organotin (IV) compounds are known to induce apoptosis via the intrinsic mitochondrial pathway, which is a key mechanism of effective anticancer therapy. Their ability to selectively promote apoptotic cell death highlights their potential as chemotherapeutic agents. In this study, the in vitro effects of two triorganotin compounds, tributyltin
Dana Strouhalova +3 more
wiley +1 more source
This paper describes the synthesis of four new organotin compounds of general formula: (Ph4P)[Sn(Cy)3(RSO2N=CS2)] [Ph4P = tetraphenylphosphonium cation, Cy = cyclohexyl, R = C6H5 (1), 4-ClC6H4 (2), 4-BrC6H4 (3) and 4-IC6H4 (4)]. They were obtained by the
Fernanda C. Bottega +5 more
doaj +1 more source
Developmental toxicity of organotin compounds in animals
Organotin compounds (OTs) have been used as biocides in antifouling paints and agriculture. The IMO introduced a global ban on the use of OTs in antifouling systems in 2001 due to their high toxicity.
Lijiao eWu +5 more
doaj +1 more source
Enhanced Dehydrogenation and Hydrogenation Capacity of Poly(5‐Vinyl‐1‐Indanol) at Low Temperatures
ABSTRACT Redox‐active polymer‐based hydrogen carriers store hydrogen gas through chemical bonding. Although existing redox‐active polymers utilized as hydrogen storage units (e.g., fluorenone and fluorenol) demonstrate reversible hydrogenation in the presence of iridium complex catalysts, they are often hindered by low weight‐based hydrogen storage ...
Yusuke Kaiwa +3 more
wiley +1 more source
Additives' structures. ABSTRACT Poly(vinyl chloride) has been a key polymeric material since its commercial production in 1931, demonstrating versatility across numerous industries due to its compatibility with various additives. PVC's inherent properties, flame retardance, durability, and recyclability make it ideal for building and construction ...
Stefano Gardi +4 more
wiley +1 more source
Intramolecular (RO)2PO→Halogen interaction versus intermolecular (RO)2PO···HOH hydrogen bonds. Although the O···I distance is shorter than the sum of the van der Waals radii of the atoms involved, there is no covalency involved in this interaction.
David Mross +6 more
wiley +1 more source
Durable Biofouling‐Resistant Coated Fabric Based on Aerogel/Polyurethane for Marine Applications
A multilayer composite protective fabric (PUC‐CME/KF) is developed by integrating carboxymethyl chitosan/coral extract aerogel and capsaicin‐loaded polyurethane onto a knitted substrate. The material exhibits exceptional extensibility (1963% elongation at break) and sustained capsaicin release.
Haoqiang Tian +10 more
wiley +1 more source
The SnIV atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octahedron.
Nur Adibah Binti Mohd Amin +5 more
doaj +1 more source

