Results 91 to 100 of about 8,906 (257)

Calculated oscillator strengths and transition probabilities of singly ionised nickel (Ni II)

open access: yesAstronomy & Astrophysics
Aims. This work reports calculated transition probabilities for spectral lines of singly ionised nickel (Ni II) incorporating newly determined experimental energy levels, addressing critical gaps in atomic data required for astrophysical spectroscopy and
Clear Christian P.   +2 more
doaj   +1 more source

Metal (n+1)p‐nd Orbital Hybridization and Excited‐State Metal–Ligand π‐Interactions Enable d10 Carbene‐Metal‐Amide TADF OLEDs with High Efficiency and Long Operational Lifetime

open access: yesAdvanced Science, EarlyView.
We elucidate the key roles of metal p‐d orbital hybridization, excited‐state metal–ligand π‐interactions, and structural rotation in TADF of d10 CMA complexes. Introducing electron‐withdrawing or π‐extended ligand substituents weakens excited‐state metal‐ligand π‐interactions and improves kTADF, but may compromise emitter stability in device operation.
Shuo Xu   +5 more
wiley   +1 more source

Synchronization‐Dissipation in the Cardiorespiratory System

open access: yesAdvanced Science, EarlyView.
By modeling central nervous coupling and viscoelastic interactions in the cardiorespiratory system we show that synchronization produces a 10% gain in cardiac efficiency in humans. It is surmised that respiratory sinus arrhythmia improves cardiac pumping efficiency by reducing dynamic stress and power dissipation in the pulmonary vasculature.
Joshua R. Border   +3 more
wiley   +1 more source

Oscillator strengths for the helium isoelectronic sequence

open access: yesJournal of Research of the National Bureau of Standards Section A: Physics and Chemistry, 1967
Variational wavefunctions have been computed for the 11S, 21, 3S, 21, 3P, 31, 3P, and 31, 3D terms of ions in the helium isoelectronic sequence from He through Ne+8. The trial functions are Hylleraas type expansions, explicitly involving r 12, and with expansion lengths of around 50 terms, differing slightly for the different states.
openaire   +2 more sources

Aromaticity‐Engineered Open‐Shell Radical Anions for Air‐Stable Doublet Emission in N‐Annulated Perylene Diimide

open access: yesAdvanced Science, EarlyView.
Open‐shell type radical anions with stable doublet emission have been synthesized that feature aromaticity engineering, through‐space charge‐transfer (TSCT), and electro(fluoro)chromism. ABSTRACT We report the doublet emissive open‐shell radical anions, where the N‐annulated perylene diimide (PDIN–H) is functionalized with aromatic rings.
Jeongyoon Kim   +4 more
wiley   +1 more source

Experimental Branching Fractions, Transition Probabilities, and Oscillator Strengths in Sm ii

open access: yesThe Astrophysical Journal Supplement Series
Branching fractions (BFs) of Sm ii for 71 lines from 12 excited levels ranging from 31,638.79 to 35,463.91 cm ^−1 were determined for the first time based on the Fourier transform spectra available from the National Solar Observatory database.
Xinghao Wang   +5 more
doaj   +1 more source

Photonic‐Enabled Energy‐Efficient Transparent Neuromorphic Computing Devices: A Review

open access: yesAdvanced Science, EarlyView.
Transparent photonic neuromorphic computing devices merge optics and brain‐inspired computing to overcome von Neumann bottlenecks with ultrafast, low‐energy processing. By exploiting transparent oxides, 2D materials, phase‐change materials, and hybrid heterostructures, these platforms enable photonic synapses, memory, and logic for see‐through edge ...
Shuvaraj Ghosh   +8 more
wiley   +1 more source

Beyond Electrostatics: Anion‐π+ Orbital Hybridization Underpins High‐Performance Chloride Storage in Poly(arylamine) Organic Cathodes

open access: yesAdvanced Science, EarlyView.
The fundamental nature of anion storage in p‐type organic cathodes is elucidated using rigid poly(arylamine) frameworks. This study reveals a hybrid covalent‐ionic mechanism for anion‐π+ interactions, driven by synergistic orbital hybridization and electrostatic attraction.
Tiantian She   +7 more
wiley   +1 more source

Electromagnetic Radiation Stimulated Learning in Perovskite Nickelates

open access: yesAdvanced Science, EarlyView.
ABSTRACT Biological plasticity refers to the ability of synapses to strengthen or weaken over time. These adaptive properties play a fundamental role in learning and memory, spanning many orders of magnitude in timescales. Short‐term plasticity (STP) arises from rapid correlative activity, while long‐term plasticity (LTP) is governed by slower ...
Ranjan Kumar Patel   +8 more
wiley   +1 more source

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