Results 11 to 20 of about 147,621 (248)
Reactional Processes on Osmium–Polymeric Membranes for 5–Nitrobenzimidazole Reduction
Membranes are associated with the efficient processes of separation, concentration and purification, but a very important aspect of them is the realization of a reaction process simultaneously with the separation process.
Aurelia Cristina Nechifor +11 more
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Summary: Mononuclear metal-peroxo species are invoked as the key intermediates in metalloenzymatic or synthetic catalysis. However, either transience or sluggishness reactivity of synthetic analogs of metal-peroxo species impedes our understanding of ...
Zhihong Deng +7 more
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While noble metals can be active electrocatalysts for producing renewable H2, there are relatively few works examining osmium materials. Here, the authors prepare boron-doped osmium aerogels for H2 evolution electrocatalysis plus examine the mechanism ...
Yinghao Li +6 more
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Process and kinetic analysis of osmium prepared by microwave sintering
Os sintered body was prepared by microwave sintering process. The influences of the green compact pressure and the microwave sintering parameters (heating rate, sintering temperature, and holding time) on the microstructure and relative density of Os ...
LIU Wei +9 more
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Seawater Chemistry and Hydrothermal Controls on the Cenozoic Osmium Cycle
Osmium isotope ratios are a key tool to track changes in global weathering and carbon cycle evolution through time. Long‐term changes in seawater Os isotope records over the Cenozoic have been used to argue for changes in weathering from increased uplift,
Joachim A. R. Katchinoff +4 more
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Anti-colorectal cancer activity of an organometallic osmium arene azopyridine complex [PDF]
This first in vivo antitumour activity for an organometallic osmium arene complex, [Os(eta(6)-p-cym)(4-(2-pyridylazo)-N,N-dimethylaniline)I]PF(6), is reported. The complex delays the growth of HCT116 human colon cancer xenografts in mice, with negligible
Cooper, Patricia A. +6 more
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Controlling platinum, ruthenium, and osmium reactivity for anticancer drug design [PDF]
The main task of the medicinal chemist is to design molecules that interact specifically with derailed or degenerating processes in a diseased organism, translating the available knowledge of pathobiochemical and physiological data into chemically ...
Bruijnincx, Pieter C. A., Sadler, P. J.
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Osmium complexes by interaction osmium bipyridyl chloride (Os(bipy)2Cl2) and dimmethylbipyridil chloride (Os(dimebipy)2Cl2) with a number of synthesised polymers on the base of 1-(3-aminepropyl)-imidazole, methylmethacrylate, acrylic acid and ...
Yu. M. Sultanov
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Tamoxifen-like metallocifens target thioredoxin system determining mitochondrial impairment leading to apoptosis in Jurkat cells [PDF]
Tamoxifen-like metallocifens (TLMs) of the group-8 metals (Fe, Ru, and Os) show strong anti-proliferative activity on cancer cell lines resistant to apoptosis, owing to their unique redox properties. In contrast, the thioredoxin system, which is involved
Alberto Bindoli +9 more
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Arene-Osmium(II) Complexes in Homogeneous Catalysis
Although the application of arene-osmium(II) complexes in homogeneous catalysis has been much less studied than that of their ruthenium analogues, different works have shown that, in some instances, a comparable or even superior effectiveness can be ...
Pascale Crochet, Victorio Cadierno
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