Results 1 to 10 of about 2,492 (186)

Fast and Stable Photochromic Oxazines. [PDF]

open access: yesThe Journal of Organic Chemistry, 2005
We have designed and synthesized two photochromic compounds incorporating fused indoline and benzooxazine fragments. Variable-temperature 1H NMR spectroscopy demonstrates that their central [1,3]oxazine ring opens thermally with free energy barriers ranging from 14 to 19 kcal mol(-1).
Tomasulo M   +3 more
openaire   +2 more sources

1,4-Oxazine

open access: yesChemical Communications, 2013
The fundamental heterocyclic compound 1,4-oxazine has been generated using FVP. It is the first parent heterocycle among all the possible isomeric oxazines, thiazines and their heavier atom analogues to be characterised spectroscopically, and is shown to exist in solution entirely as the 4H-isomer.
Aitken, R Alan   +4 more
openaire   +5 more sources

Easy Access to New Heterocyclic Systems:  1,4-Oxazine and Substituted 1,4-Oxazines [PDF]

open access: yesThe Journal of Organic Chemistry, 2007
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Elise, Claveau   +4 more
openaire   +2 more sources

CCXXXIX.—A new synthesis of oxazines [PDF]

open access: yesJ. Chem. Soc., Trans., 1921
n ...
Fairbourne, Arthur, Toms, Harold
openaire   +2 more sources

Thermoresponsive Poly(2‐oxazine)s

open access: yesMacromolecular Rapid Communications, 2011
AbstractThe monomers 2‐methyl‐2‐oxazine (MeOZI), 2‐ethyl‐2‐oxazine (EtOZI), and 2‐n‐propyl‐2‐oxazine (nPropOZI) were synthesized and polymerized via the living cationic ring‐opening polymerization (CROP) under microwave‐assisted conditions. pEtOZI and pnPropOZI were found to be thermoresponsive, exhibiting LCST behavior in water and their cloud point ...
Bloksma, M.M.   +6 more
openaire   +3 more sources

Allosteric Regulation of Photophysics and Binding in Oxazine‐macrocycle Complexes at Single‐molecule Resolution

open access: yesAngewandte Chemie International Edition, EarlyView.
This work explores the interactions between the oxazine dye ATTO655 and two macrocyclic hosts using optical (single‑molecule) spectroscopy. Although ATTO655 forms a classical inclusion complex with cucurbit[8]uril (CB8), its interaction with p‑sulfonatocalix[4]arene (sCX4) leads to the formation of dim exclusion complexes.
Siyu Lu   +7 more
wiley   +1 more source

Monosubstituted N‐Arylhydroxylamine Chemistry: Integrating Contemporary Synthetic Approaches for the Efficient Construction of Diverse Heterocyclic Scaffolds

open access: yesChemistry – A European Journal, EarlyView.
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis   +2 more
wiley   +1 more source

Sulfur‐Rich Sustainable Copolymers for Enhancing Redox Kinetics and Alleviating Cathode Passivation in Lithium‐Sulfur Batteries

open access: yesExploration, EarlyView.
A molecularly engineered, sustainable sulfur‐rich redox copolymer cathode delivers accelerated sulfur conversion and suppressed passivation, enabling high sulfur utilization and durable, high‐performance LiS batteries. ABSTRACT Lithium‐sulfur (Li‐S) batteries are promising candidates for advanced energy storage systems.
Sangeeta Sahu   +8 more
wiley   +1 more source

Mechanophores for Mechano‐Imaging in Polymeric Materials

open access: yesHelvetica Chimica Acta, EarlyView.
Mechanophore‐based mechanochromic systems convert mechanical forces in polymers into optical signals, enabling direct imaging of stress localization and molecular damage. This perspective highlights recent advances in mechanophore design and their use to probe local mechanics across diverse polymer matrices, and concludes by outlining opportunities for
Jess M. Clough
wiley   +1 more source

A Non‐Antigenic Randomized Polyethylene Glycol/Poly(2‐Phenyl‐2‐Oxazine)‐Based Drug Delivery Platform

open access: yesMacromolecular Rapid Communications, EarlyView.
Randomized PEG (rPEG), a conceptually new PEG alternative, is combined with poly(2‐phenyl‐2‐oxazine) (PPheOzi) to establish an rPEG‐b‐PPheOzi‐b‐rPEG micellar drug delivery platform. The PPheOzi block enables high drug loadings, while competitive ELISA reveals a drastic reduction in anti‐PEG antibody affinity of rPEG in comparison to PEG.
Julian Schmidt   +6 more
wiley   +1 more source

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