Results 111 to 120 of about 462,913 (290)

Analytical study of mechanisms for nitric oxide formation during combustion of methane in a jet-stirred combustor [PDF]

open access: yes
The role of chemical kinetics in the formation of nitric oxide during the combustion of methane was examined analytically by means of a detailed chemical mechanism for the oxidation of methane, for the reaction between hydrocarbon fragments, and for the ...
Jachimowski, C. J.
core   +1 more source

Structure and oxidation kinetics of the Si(100)-SiO2 interface

open access: yes, 1998
We present first-principles calculations of the structural and electronic properties of Si(001)-SiO2 interfaces. We first arrive at reasonable structures for the c-Si/a-SiO2 interface via a Monte-Carlo simulated annealing applied to an empirical ...
A. Atkinson   +32 more
core   +1 more source

Highly Sensitive Electrochemical Biosensor Based on Hairy Particles with Controllable High Enzyme Loading and Activity

open access: yesAdvanced Functional Materials, EarlyView.
For the first time, a highly sensitive electrochemical biosensor based on SiO2‐based hairy particles with a grafted PDMAEMA polymer brush containing a quantifiable and large amount of immobilized Laccase is reported. The fabricated biosensor exhibits a sensitivity of 0.14 A·m⁻¹, a limit of detection (LOD) of 0.1 µm, and a detection range of 0.3–750 µm,
Pavel Milkin   +7 more
wiley   +1 more source

Kinetics of oxidation of D-arabinose and D-xylose by vanadium (V) in the presence of manganese II as homogeneous catalyst

open access: yesOrbital: The Electronic Journal of Chemistry, 2010
Kinetics of oxidation of D-arabinose and D-xylose by acidic solution of vanadium (V) ions in the presence of manganese (II) has been reported. First-order dependence of the reaction rate was observed on [sugars] and [H+] at low concentrations throughout ...
Ezekiel O. Odebunmi   +2 more
doaj   +1 more source

Biomass Native Structure Into Functional Carbon‐Based Catalysts for Fenton‐Like Reactions

open access: yesAdvanced Functional Materials, EarlyView.
This study indicates that eight biomasses with 2D flaky and 1D acicular structures influence surface O types, morphology, defects, N doping, sp2 C, and Co nanoparticles loading in three series of carbon, N‐doped carbon, and cobalt/graphitic carbon. This work identifies how these structural factors impact catalytic pathways, enhancing selective electron
Wenjie Tian   +7 more
wiley   +1 more source

Tuning the Dielectric Properties of Individual Clay Nanosheets by Interlayer Composition: Toward Nano‐Electret Materials

open access: yesAdvanced Functional Materials, EarlyView.
The dielectric properties of clays are studied on the level of individual monolayers and functional double stacks. The material breakdown characteristics and charge storage performance are analyzed. For illustration, a defined charge pattern representing a cuneiform character is produced, written into a microscopic clay tile, referencing the origins of
Sebastian Gödrich   +6 more
wiley   +1 more source

Oxidation kinetics and non-Marcusian charge transfer in dimensionally confined semiconductors. [PDF]

open access: yesNat Commun, 2023
Xu N   +10 more
europepmc   +1 more source

Exploiting the Functionality of Cerium Oxide‐Modified Carbon Nanohorns Catalysts Toward Enhanced CO2 Reduction Performance

open access: yesAdvanced Functional Materials, EarlyView.
A cerium oxide‐carbon nanohybrid catalyst is synthesized via two distinct routes and is integrated into H‐type cells and gas diffusion layers (GDLs) to enhance electrochemical performance. Structural variations significantly affect performance, with the solvothermal sample exhibiting higher current densities.
Alessia Pollice   +9 more
wiley   +1 more source

A model for the degradation of polyimides due to oxidation

open access: yes, 2010
Polyimides, due to their superior mechanical behavior at high temperatures, are used in a variety of applications that include aerospace, automobile and electronic packaging industries, as matrices for composites, as adhesives etc.
C.M. Falcone   +25 more
core   +1 more source

Modulating Electrochemical CO2 Reduction Pathways via Interfacial Electric Field

open access: yesAdvanced Functional Materials, EarlyView.
Engineering interfacial electric fields in Cu/ITO electrodes enables precise control of CO2 reduction pathways. Charge transfer from Cu to ITO generates positively charged Cu species that steer selectivity from ethylene toward methane. This work demonstrates how interfacial electric‐field modulation can direct reaction intermediates and transform ...
Mahdi Salehi   +7 more
wiley   +1 more source

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