Results 31 to 40 of about 13,910,228 (354)
Angewandte Chemie, 2016 AbstractIn a recent paper, Wang et al. found an iridium‐containing compound with a formal oxidation state of 9. This is the highest oxidation state ever found in a stable compound. To learn if this is the highest chemical oxidation state possible, Kohn–Sham density functional theory was used to study various compounds, including PdO42+, PtO42+, PtO3F22+
Haoyu S. Yu, Donald G. Truhlar
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Journal of Chemical Physics, 2020 Transition metal oxides are of high interest in both energy storage (batteries) and production of non-fossil fuels by (photo)electrocatalysis. Their functionally crucial charge (oxidation state) changes and electrocatalytic properties are best ...
Chiara Pasquini +3 more
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Iodine-catalyzed diazo activation to access radical reactivity
Nature Communications, 2018 Radical reactivity of diazo compounds, useful organic building blocks, is yet underexplored. Here, the authors report an iodine-catalyzed radical activation of diazo compounds affording a variety of substituted cyclopropanes, pyrroles and epoxides under ...
Pan Li +5 more
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Critical evaluation of potentiometric redox titration in enology [PDF]
, 2005 Measurements of the zero current potential of a platinum electrode immersed in solutions of tanins or in wines of various origins, were performed during the additions of a solution of Ti(III), or of a solution of dichlorophenolindophenol (DCPIP), in ...
Comtat, Maurice, Durliat, Hélène
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Beilstein Journal of Nanotechnology, 2022 In this study, we present theoretical X-ray absorption near-edge structure (XANES) spectra at the K-edge of oxygen in zirconia containing Ni dopant atoms and O vacancies at varying concentrations.
Dick Hartmann Douma +6 more
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Oxidized Lipids in Persistent Pain States [PDF]
Frontiers in Pharmacology, 2019 Chemotherapy, nerve injuries, or diseases like multiple sclerosis can cause pathophysiological processes of persistent and neuropathic pain. Thereby, the activation threshold of ion channels is reduced in peripheral sensory neurons to normally noxious stimuli like heat, cold, acid, or mechanical due to sensitization processes.
Osthues, Tabea, Sisignano, Marco
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Polyoxometalate-Based Catalysts for CO2 Conversion
Molecules, 2019 Polyoxometalates (POMs) are a diverse class of anionic metal-oxo clusters with intriguing chemical and physical properties. Owing to unrivaled versatility and structural variation, POMs have been extensively utilized for catalysis for a plethora of ...
Yanwei Cao +3 more
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Graphitic phosphorus coordinated single Fe atoms for hydrogenative transformations
Nature Communications, 2020 Phosphorus ligands have been extensively used in metal complexes for homogeneous catalysis. Here, the authors broaden this scope to heterogeneous catalysis by preparing a P-coordinated Fe single atom catalyst with excellent catalytic performance in ...
Xiangdong Long +8 more
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The dn Number in Transition Metal Chemistry: Its Utility and Limitations
Chemistry, 2023 The dn number or configuration is a very useful parameter in transition metal chemistry because it conveys information about the expected properties of a d-block metal complex, including its shape, magnetism, thermodynamic stability, kinetic lability ...
Nicholas C. Norman, Paul G. Pringle
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Dynamic charge and oxidation state of Pt/CeO2 single-atom catalysts
Nature Materials, 2019 The catalytic activity of metals supported on oxides depends on their charge and oxidation state. Yet, the determination of the degree of charge transfer at the interface remains elusive.
Nathan Daelman +2 more
semanticscholar +1 more source