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Oxidative Decarboxylation of Levulinic Acid by Cupric Oxides [PDF]

open access: yesMolecules, 2010
In this paper, cupric oxides was found to effectively oxidize levulinic acid (LA) and lead to the decarboxylation of levulinic acid to 2-butanone.
Lu Lin   +3 more
doaj   +5 more sources

The Generation of the Oxidant Agent of a Mononuclear Nonheme Fe(II) Biomimetic Complex by Oxidative Decarboxylation. A DFT Investigation [PDF]

open access: yesMolecules, 2020
The oxidative decarboxylation of the iron(II) α-hydroxy acid (mandelic acid) complex model, biomimetic of Rieske dioxygenase, has been investigated at the density functional level.
Angela Parise   +4 more
doaj   +2 more sources

Amino acid decarboxylation preserves Salmonella fitness during phagocyte-derived oxidative stress [PDF]

open access: yesmBio
Successful establishment of infection by non-typhoidal Salmonella depends upon its ability to resist the antimicrobial defenses of the host innate immune response. To withstand the membrane depolarization that potentiates the killing activity of reactive
Alyssa Margolis   +5 more
doaj   +2 more sources

In vitro oxidative decarboxylation of free fatty acids to terminal alkenes by two new P450 peroxygenases [PDF]

open access: yesBiotechnology for Biofuels, 2017
Background P450 fatty acid decarboxylases represented by the unusual CYP152 peroxygenase family member OleTJE have been receiving great attention recently since these P450 enzymes are able to catalyze the simple and direct production of 1-alkenes for ...
Huifang Xu   +10 more
doaj   +2 more sources

Oxidative Decarboxylation of Levulinic Acid by Silver(I)/Persulfate [PDF]

open access: yesMolecules, 2011
The oxidative decarboxylation of levulinic acid (LA) by silver(I)/persulfate [Ag(I)/S2O82−] has been investigated in this paper. The effects of buffer solution, initial pH value, time and temperature and dosages of Ag(I)/S2O82− on the decarboxylation of ...
Yan Gong, Lu Lin
doaj   +2 more sources

Oxidative decarboxylation of retinoic acid in microsomes of rat liver and kidney

open access: hybridJournal of Lipid Research, 1968
Liver and kidney microsomes have been found to catalyze a rapid decarboxylation of retinoic acid in vitro. The reaction requires NADPH and Fe2+, and is further stimulated by the presence of pyrophosphate.
Anita B. Roberts, Hector F. DeLuca
doaj   +2 more sources

Linked cycles of oxidative decarboxylation of glyoxylate as protometabolic analogs of the citric acid cycle [PDF]

open access: yesNature Communications, 2018
The citric acid cycle (TCA) is a fundamental metabolic pathway to release stored energy in living organisms. Here, the authors report two linked cycles of reactions that each oxidize glyoxylate into CO2 and generate intermediates shared with the modern ...
Greg Springsteen   +4 more
doaj   +2 more sources

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