Results 261 to 270 of about 43,763 (313)

Ni‐Catalyzed Electrochemical Carbonylative Ketone Synthesis Employing a Radical Sorting Strategy

open access: yesAngewandte Chemie, Volume 138, Issue 2, 9 January 2026.
An electrolytic‐Ni‐catalyzed general synthesis of ketones was reported, utilizing radicals and carbon monoxide as partners. The radical sorting effect was proposed within an outer sphere addition mechanism of alkyl radicals to Ni‐stabilized ketyl radicals, thereby facilitating selectivity among different radicals. This protocol allows for a broad range
Jinkun Fan   +3 more
wiley   +2 more sources

Cyclopropenes in Photochemical Reactions

open access: yesChemistry – A European Journal, Volume 32, Issue 3, 16 January 2026.
The photochemical side of cyclopropenes. Cyclopropenes are valuable synthetic tools in organic chemistry. In particular, this review focuses on the photochemistry of cyclopropenes. The reactivity of cyclopropenes excited by irradiation is discussed showing their unique potential for organic synthesis.
David Suárez‐García   +2 more
wiley   +1 more source

Utilizing Similarity Measures to Map Chemical Reactivity

open access: yesAngewandte Chemie, Volume 138, Issue 2, 9 January 2026.
Autonomous chemistry demands unbiased, adaptable tools for monitoring reactivity. We present a general method using similarity analysis of spectroscopic data, independent of prior knowledge. Demonstrated across diverse techniques and reactions, this approach reveals kinetics and dynamics, establishing a foundation for self‐guided chemical platforms and
Robert Rauschen   +2 more
wiley   +2 more sources

Chemoselective Divergence via Substrate Control: Decarboxylative and Decarbonylative Coupling of 2‐Oxoacids with Allylic Difluorides

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 1, January 12, 2026.
A photocatalytic method for the decarboxylative CC coupling of 2‐oxoacids and allylic difluorides has been developed, yielding monofluoroalkenes in excellent yields. The reaction tolerates both aryl‐ and alkyl‐substituted 2‐oxoacids and displays high functional group tolerance.
Taylor Semeniuk   +4 more
wiley   +1 more source

Biodegradation of perfluorooctanoic acid (PFOA) by laccase from Agaricus bisporus via oxidative decarboxylation

open access: gold
Mengistu F. Mekureyaw   +5 more
openalex   +1 more source

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