Ni‐Catalyzed Electrochemical Carbonylative Ketone Synthesis Employing a Radical Sorting Strategy
An electrolytic‐Ni‐catalyzed general synthesis of ketones was reported, utilizing radicals and carbon monoxide as partners. The radical sorting effect was proposed within an outer sphere addition mechanism of alkyl radicals to Ni‐stabilized ketyl radicals, thereby facilitating selectivity among different radicals. This protocol allows for a broad range
Jinkun Fan +3 more
wiley +2 more sources
Hydrazine Derivatives as C-Centered Radical Precursors for C-C Bond Formation Reactions. [PDF]
Lopat'eva ER, Krylov IB, Terent'ev AO.
europepmc +1 more source
Cyclopropenes in Photochemical Reactions
The photochemical side of cyclopropenes. Cyclopropenes are valuable synthetic tools in organic chemistry. In particular, this review focuses on the photochemistry of cyclopropenes. The reactivity of cyclopropenes excited by irradiation is discussed showing their unique potential for organic synthesis.
David Suárez‐García +2 more
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Utilizing Similarity Measures to Map Chemical Reactivity
Autonomous chemistry demands unbiased, adaptable tools for monitoring reactivity. We present a general method using similarity analysis of spectroscopic data, independent of prior knowledge. Demonstrated across diverse techniques and reactions, this approach reveals kinetics and dynamics, establishing a foundation for self‐guided chemical platforms and
Robert Rauschen +2 more
wiley +2 more sources
Urinary Porphyrin Profiles and Trace Element Imbalances in Children with Autism Spectrum Disorders: Insights into Environmental and Metabolic Biomarkers. [PDF]
Osredkar J +5 more
europepmc +1 more source
A photocatalytic method for the decarboxylative CC coupling of 2‐oxoacids and allylic difluorides has been developed, yielding monofluoroalkenes in excellent yields. The reaction tolerates both aryl‐ and alkyl‐substituted 2‐oxoacids and displays high functional group tolerance.
Taylor Semeniuk +4 more
wiley +1 more source
Engineering a dual-cycle carbon fixation system for enhanced biomass and lipid production in plants. [PDF]
Xu C, Yan S, Hou Y, Zhao L.
europepmc +1 more source
Combined extraction and spray-freeze-drying of Cannabis sativa Flos provides stable lyophilizate particles of cannabinoids. [PDF]
Kožák J +4 more
europepmc +1 more source
LMCT-Driven Iron Photocatalysis: Mechanistic Insights and Synthetic Applications. [PDF]
Chaudhuri A +4 more
europepmc +1 more source

